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Solute Transport In A Porous Medium: A Mass-Conserving Solution For The Convection-Dispersion Equation In A Finite Domain, William Golz

LSU Doctoral Dissertations

This dissertation considers the proper mathematical description for the physical problem of a miscible solute undergoing longitudinal convective-dispersive transport with constant production, first-order decay, and equilibrium sorption in a porous medium. Initial and input concentrations may be any continuously differentiable functions and the mathematical system is articulated for a finite domain. This domain yields a mass balance which requires Robin (i.e., third-type) boundaries, which describe a continuous flux but a discontinuous resident-concentration. The discontinuity in the resident concentration at the outflow boundary yields an underdetermined system when the exit concentration is not experimentally measured. This is resolved by defining the …