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Cement-Based Nanocomposites With Tunable Electrical And Thermal Conductivity, Myrsini Maglogianni

Civil Engineering Dissertations

ABSTRACT: While concrete, the most widely used construction material exhibits low electrical and thermal conductivity, it can be engineered at the nanoscale to exhibit energy-related functionalities. This dissertation aims to develop nanoengineered cementitious composites with high electrical conductivity and tunable thermal conductivity to enable energy-related functionalities such as electricity generation and thermal heating capabilities. Highly dispersed nanostructured materials with different intrinsic properties were used to modify the thermal and electrical properties of the developed cementitious composites to enable their thermoelectric (TE) and/or electrothermal (ET) characteristics. One of the objectives of this research was to optimize the electrical-to-thermal energy conversion capability …

Moisture Dependence Of Electrical Resistivity In Under-Percolated Cement-Based Composites With Multi-Walled Carbon Nanotubes, Geuntae Hong, Seongcheol Choi, Doo-Yeol Yoo, Taekgeun Oh, Yooseob Song, Jung Heum Yeon

Civil Engineering Faculty Publications and Presentations

Cement-based piezoresistive composites have attracted significant attention as smart construction materials for embedding self-sensing capability in concrete infrastructure. Although a number of studies have been conducted using multi-walled carbon nanotubes (MWCNTs) as a functional filler for self-sensing cement-based composites, studies addressing the influence of the internal moisture state on the electrical properties are relatively scant. In this study, we aim to experimentally investigate the effect of internal moisture state on the electrical resistivity of cement-based composites containing MWCNTs as an electrically conductive medium to raise a need for calibration of self-sensing data considering the internal moisture state. To this end, …

Design And Predicting Performance Of Carbon Nanotube Reinforced Cementitious Materials : Mechanical Properties And Dispersion Characteristics., Mahyar Ramezani

Electronic Theses and Dissertations

Recently, Carbon Nanotubes (CNTs) are drawing considerable attention of researchers for reinforcing cementitious materials due to their excellent mechanical properties and high aspect ratio (length-to-diameter ratio). However, CNTs might not disperse well within the cement matrix, resulting in little improvement or even degradation of concrete properties. The uncertainty in producing the consistent results in different studies might be attributed to multiple interactions between the experimental variables affecting the nanotube dispersion and the final properties of CNT-cement nanocomposites. Therefore, this research mainly focused on proposing equations that can reliably capture these interactions in order to correlate CNT dispersion with the mechanical …

Degradation Of Emerging Contaminants By Advanced Oxidation Using Multi-Walled Carbon Nanotubes And Continuous Ozone Injection, Emily N. Miller

Master's Theses

With a growing population and continuous accumulation of pollutants, water resources worldwide are quickly being depleted. Drastic improvements need to be made in both water conservation and treatment. Advanced oxidation processes (AOPs) have been developed to go above and beyond the capabilities of traditional wastewater treatment facilities to eliminate emerging contaminants from our water systems. AOPs increase the generation of hydroxyl radicals (•OH) in oxidation reactions, which are less selective and more reactive than other oxidants, such as ozone, so they are more effective at degrading persistent compounds. This study explored an AOP that utilizes ozonated multi-walled carbon nanotubes (MWCNTs) …

Mechanical Characterization Of Polymer Concrete With Nanomaterials, Alaeddin Douba

Civil Engineering ETDs

Nanomaterials are defined by those whose characteristic length scale lies within the nanometer scale. Their extreme dimension achieves extraordinary mechanical properties superior to other micro and macro additives. The introduction of nanotechnology to Civil Engineering utilizes low volume inclusions of nanomaterials to alter the properties of conventionally used bulk materials. Polymer Concrete (PC) where epoxy polymer binders replace cement binders, has become a common repair material among many other application and often can be considered an alternative to Portland cement concrete (PCC). PC is often used in bridge deck overlays, manholes, machine foundations and repairs. Its diverse chemical composition and …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …

Application Of Various Adsorbents To Remove Micro-Pollutants In Aquatic System, Chanil Jung

Theses and Dissertations

Untreated or insufficiently treated pharmaceuticals and endocrine disrupting compounds (EDCs) as well as heavy metals have influenced the ecosystem and their exposures in the water system have threatened human health; causing cancers and adverse health effect to immune system. While various water treatment techniques have been applied to solve this problem, adsorption has been considered as one of the most efficient and manageable water purification techniques. Advanced analysis methods for aqueous contaminants have improved comprehension, allowing proficiency about the fate of trace leveled emerging contaminants, thus allowed to reveal the adsorption mechanisms of each pollutant. This dissertation focuses on the …

Experimental Tools To Study Molecular Recognition Within The Nanoparticle Corona, Markita P. Landry, Sebastian Kruss, Justin T. Nelson, Gili Bisker, Nicole M. Iverson, Nigel F. Reuel, Michael S. Strano

Department of Biological Systems Engineering: Papers and Publications

Advancements in optical nanosensor development have enabled the design of sensors using synthetic molecular recognition elements through a recently developed method called Corona Phase Molecular Recognition (CoPhMoRe). The synthetic sensors resulting from these design principles are highly selective for specific analytes, and demonstrate remarkable stability for use under a variety of conditions. An essential element of nanosensor development hinges on the ability to understand the interface between nanoparticles and the associated corona phase surrounding the nanosensor, an environment outside of the range of traditional characterization tools, such as NMR. This review discusses the need for new strategies and instrumentation to …