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Nanopesticide Influence On Nitrogen Cycling In Soils, Jacob Richardson Jan 2023

Nanopesticide Influence On Nitrogen Cycling In Soils, Jacob Richardson

Theses and Dissertations--Biosystems and Agricultural Engineering

Nanotechnology has several applications in the agricultural industry, as the small size of nanoparticles and high reactivity enables targeted delivery of pesticides and fertilizers to the intended crop. Copper-based nanopesticides such as Kocide, are proposed as a more efficient method for targeted pest control. Despite the potential benefits of nanopesticides, little is known regarding the transport and implications of nanopesticides under long-term inundation conditions often found in downstream wetlands. Specifically, the impact of nanopesticides on microbial nitrogen processes in wetland environments remains unknown. Therefore, this thesis explores the impact of nanopesticides, specifically Kocide, on microbial nitrogen cycles in agricultural and …


Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley Jan 2022

Using Stream Restoration To Mitigate Stormwater Runoff In An Urban Watershed: A Case Study, Jonathan M. Brantley

Theses and Dissertations--Biosystems and Agricultural Engineering

The goal of this case study was to evaluate the effectiveness a 275 m regenerative stream restoration design to mitigate stormwater runoff in a highly urbanized watershed. The restoration resulted in a wide, wetland-like floodplain, comprised of a rock base that was overtopped with a filtration media (approximately 30% woodchips and 70% topsoil). The creation of the floodplain-wetland complex in tandem with filtration media lead to increased storage capacity and an increase in hyporheic exchange within the system. Significant reductions were found for the storm hydrograph parameters volume, peak discharge, and time to peak. Reductions in baseflows were also noted …


Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti Jan 2022

Classifying And Mapping Aquatic Vegetation In Heterogeneous Stream Ecosystems Using Visible And Multispectral Uav Imagery, Rozalia Agioutanti

Theses and Dissertations--Biosystems and Agricultural Engineering

The need for assessment and management of aquatic vegetation in stream ecosystems is recognized given the importance in impacting water quality, hydrodynamics, and aquatic biota. However, existing approaches to monitor are laborious and its currently not feasible to track spatial and temporal differences at broad scales. The objective of this study was therefore to map and classify aquatic vegetation of a shallow stream with heterogenous mixtures of emergent and submerged aquatic vegetation. Data was collected in the Camden Creek watershed within the Inner Bluegrass Region of central Kentucky. The use of unmanned aerial vehicles (UAVs) was employed and both visible …


Sediment Nitrogen Dynamics In Backwater Wetland Confluences Of A Regulated River, Gina Degraves Jan 2022

Sediment Nitrogen Dynamics In Backwater Wetland Confluences Of A Regulated River, Gina Degraves

Theses and Dissertations--Biosystems and Agricultural Engineering

As harmful algal blooms in regulated river systems have increased in the past decade, the importance of understanding sediment nutrients has also increased. Research linking nutrient processes and fine sediment dynamics to harmful algal blooms in confluence wetlands along regulated rivers has recently become apparent. However, the relationship between sediment nutrient dynamics in confluence wetlands has been understudied. Utilization of sediment fingerprinting, high-frequency water quality monitoring, and tracer unmixing mass-balance modeling, was able to suggest sediment N mineralization in Appalachia confluence riparian wetland was not a dominate source of nitrate downstream. Further measures of supplementary tracers and additional sediment sources …


Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill Jan 2022

Assessing Machine Learning Utility In Predicting Hydrologic And Nitrate Dynamics In Karst Agroecosystems, Timothy Mcgill

Theses and Dissertations--Biosystems and Agricultural Engineering

Seasonal hypoxia in the Gulf of Mexico and harmful algal blooms experienced in many inland freshwater bodies is partially driven due to excessive nitrogen loading seen from agricultural watersheds. Within the Mississippi/Atchafalaya River Basin, many areas are underlain with karst features, and efforts to reduce nitrogen contributions from these areas have had varying success, due to lacking a complete understanding of nutrient dynamics in karst agricultural systems. To improve the understanding of nitrogen cycling in these systems, 35 months of high resolution in situ water quality and atmospheric data were collected and fed into a two-hidden layer extreme learning machine …


Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff Jan 2021

Quantifying The Source And Pathway Of Dissolved Reactive Phosphate In Karst Drainage Of The Inner-Bluegrass, Cory Radcliff

Theses and Dissertations--Biosystems and Agricultural Engineering

In the Midwestern U.S. seasonal hypoxia experienced in the Gulf of Mexico and harmful algal blooms in inland freshwater ponds, lakes, and rivers are partly fueled by dissolved orthophosphate loadings from disturbed landscapes. Efforts to reduce dissolved reactive phosphate (DRP) loadings have had varying levels of success and have led to insufficient water quality improvements. Inefficiencies in conservation strategies can stem from poor understanding of phosphate source and flow pathway dynamics. This study focused on monitoring sources and flow pathways of dissolved reactive P in a karst agroecosystem with phosphatic limestone. We collected event water samples at the Camden Creek …


Impact Of Preferential Flow, Source Water Connectivity, And Agricultural Management Practices On Sediment And Particulate Phosphorus Dynamics In Midwestern Tile-Drained Landscapes, Saeid Nazari Jan 2021

Impact Of Preferential Flow, Source Water Connectivity, And Agricultural Management Practices On Sediment And Particulate Phosphorus Dynamics In Midwestern Tile-Drained Landscapes, Saeid Nazari

Theses and Dissertations--Biosystems and Agricultural Engineering

Tile drainage is recognized as a significant transporter of sediment and particulate phosphorus (PP) in the Midwestern U.S., leading to proliferation of Harmful Algal Blooms (HABs). Numerous studies have focused on Dissolved Reactive Phosphorus (DRP) and Nitrogen (N) flux dynamics in tile-drained landscapes; however, the impact of preferential flow and agricultural management practices on fate and transport of sediment and PP has remained poorly understood. The overarching objective of this study was to improve understanding of sediment P delivery in tile-drained landscapes. This dissertation focuses on four studies. In the first study, forms and flow pathway dynamics of total phosphorus …


Evaluating The Biotic Condition Of Restored Streams In Kentucky’S Inner Bluegrass Region, Charles Cole Crankshaw Jan 2021

Evaluating The Biotic Condition Of Restored Streams In Kentucky’S Inner Bluegrass Region, Charles Cole Crankshaw

Theses and Dissertations--Biosystems and Agricultural Engineering

Numerous stream restoration projects have been implemented in Kentucky’s Inner Bluegrass region to offset anthropogenic impacts. These projects range from full channel realignments to volunteer-led riparian installations. To assess the ability of said projects to restore stream habitat and biota, full restoration (n=12) and riparian (n=6) sites were compared to reference (n=6) and disturbed (n=12) sites using RBP and SVAP protocols, macroinvertebrate samples, and geomorphology. General trends for SVAP, RBP, and BI scores, starting with highest habitat or biotic quality, were reference sites, full and riparian restoration sites, then disturbed sites. The number of EPT taxa, another indicator of biological …


Soil Bulk Density Effects On Runoff Estimation, Colton Pugh Jan 2020

Soil Bulk Density Effects On Runoff Estimation, Colton Pugh

Theses and Dissertations--Biosystems and Agricultural Engineering

Urbanization has long been a major factor in the hydrology of surrounding areas. Engineers are commonly tasked with mitigating the extra runoff that urbanization brings with it. The NRCS Curve Number (CN) method is a commonly-used approach to predicting the amount of runoff that will be experienced from a given area. However, this method is known to be highly simplified in model of the processes involved. This study focused on determining the relationships between soil bulk density, simulated rainfall events, hydrologic soil group (HSG) and runoff estimation (specifically via the NRCS CN method). It was determined that soil bulk density …


Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell Jan 2020

Quantifying Nitrogen Fate In Karst Agroecosystem Streams Of Central Kentucky: Development And Application Of Numerical Modeling And Insight From High-Resolution Sensors, Nolan Lewis Bunnell

Theses and Dissertations--Biosystems and Agricultural Engineering

In-stream fate of nutrients in karst agroecosystems remains poorly understood, despite the known impact of karst on water resources at local to global scales. In the Inner-Bluegrass region of central Kentucky, heterogeneity of karst maturity, flow pathways, and nutrient sources adds to the complexity of quantifying nutrient dynamics, thus requiring novel monitoring and modeling approaches. The significance of these streams is recognized given spring/surface water confluences have been identified as hotspots for biogeochemical transformations. In slow-moving streams high in dissolved inorganic nutrients (particularly dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP)), benthic and floating aquatic macrophytes are recognized to …


High Resolution Sensing Of Nitrate Dynamics In A Mixed-Use Appalachian Watershed: Quantifying Nitrate Fate And Transport As Influenced By A Backwater Riparian Wetland, Alexandria Kosoma Jensen Jan 2018

High Resolution Sensing Of Nitrate Dynamics In A Mixed-Use Appalachian Watershed: Quantifying Nitrate Fate And Transport As Influenced By A Backwater Riparian Wetland, Alexandria Kosoma Jensen

Theses and Dissertations--Biosystems and Agricultural Engineering

As harmful algal blooms begin to appear in unexpected places such as rivers in predominantly forested systems, a better understanding of the nutrient processes within these contributing watersheds is necessary. However, these systems remain understudied. Utilization of high-resolution water quality data applied to deterministic numerical modeling has shown that a 0.42% watershed area backwater riparian wetland along the Ohio River floodplain can attenuate 18.1% of nitrate discharged from local mixed-use watersheds and improves in performance during high loading times due to coinciding increased hydrological connectivity and residence times of water in these wetlands. Loading from the Fourpole Creek watershed was …


Impact Of Climate Change On Extreme Hydrological Events In The Kentucky River Basin, Somsubhra Chattopadhyay Jan 2017

Impact Of Climate Change On Extreme Hydrological Events In The Kentucky River Basin, Somsubhra Chattopadhyay

Theses and Dissertations--Biosystems and Agricultural Engineering

Anthropogenic activities including urbanization, rapid industrialization, deforestation and burning of fossil fuels are broadly agreed on as primary causes for ongoing climate change. Scientists agree that climate change over the next century will continue to impact water resources with serious implications including storm surge flooding and a sea level rise projected for North America. To date, the majority of climate change studies conducted across the globe have been for large-sized watersheds; more attention is required to assess the impact of climate change on smaller watersheds, which can help to better frame sustainable water management strategies.

In the first of three …


Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright Jan 2016

Long-Term Effects Of Forestry Best Management Practices On Hydrology And Water Chemistry In Three Appalchian Headwater Catchments, Kameryn I. Wright

Theses and Dissertations--Biosystems and Agricultural Engineering

In 1982, a study was initiated in the Field Branch watershed, in the University of Kentucky’s Robinson Forest, to evaluate forestry best management practice (BMP) effectiveness after intensive harvesting. The study utilized a paired watershed approach on three adjacent Field Branch subcatchments. One subcatchment was left as the control, one had BMPs implemented (including a 50-ft undisturbed buffer along the stream), and one was clear-cut to the stream’s banks without the use of BMPs (i.e. logger’s choice). Prior research has shown that logging can negatively impact watershed functions by altering stream hydrology, geomorphology, water quality, and instream habitat. Thus, the …


Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry Jan 2016

Development Of Regional And Hydraulic Geometry Curves For The Eastern Kentucky Coalfields, Ashlan Berry

Theses and Dissertations--Biosystems and Agricultural Engineering

Regional curves and hydraulic geometry curves relate bankfull channel dimensions to drainage area and bankfull discharge, respectively. These curves are used in the natural channel design process to help identify bankfull and to estimate bankfull dimensions of the design channel. Nineteen streams were surveyed to determine their bankfull parameters (cross-sectional area, width, mean depth, discharge, slope, and Manning’s n), along with 27 streams previously surveyed in other studies. The data were used to create regional and hydraulic geometry curves for three hydrologic landscape regions (HLR 9, HLR 11, and HLR 16, individually) in the Eastern Kentucky Coalfields (EKC) as well …


Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith Jan 2015

Characterization Of Two Biochars Derived From Horse Muck And Their Ability To Reduce Pathogen Transport In Soil, David Griffith

Theses and Dissertations--Biosystems and Agricultural Engineering

Biochars have been created and characterized from a variety livestock manure biomass including poultry, dairy, and swine. However, no research has been conducted on the physical and chemical makeup of biochar pyrolyzed from horse muck. Two horse muck derived biochars containing either straw (HS) or woodchip (HW) bedding were pyrolyzed at 700°C and characterized for their physical and chemical properties. Tests revealed both biochars had high alkalinity, moderate specific conductivity, and low surface area as compared to other biochars in the literature. HS contained more mineral structures than HW. Scanning electron microscopy presented differences in particle shape, size, and presence …


Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch Jan 2015

Development Of Techniques For Assessing And Restoring Streams On Surface Mined Lands, Whitney Cole Blackburn-Lynch

Theses and Dissertations--Biosystems and Agricultural Engineering

Surface mining is a commonly used method for extracting coal in the Appalachian Coalfields of the U.S. This mining practice produces excess spoil or overburden, which is often placed in adjacent valleys resulting in the creation of valley fills. These valley fills bury headwater streams, which in turn can negatively impact downstream ecosystems. In 2008, the University of Kentucky designed and constructed 1,020 m of ephemeral, intermittent and headwater streams on an existing valley fill (Guy Cove) as a proof-of-concept. The goal of the project was to evaluate whether or not a stream recreation could occur on mined lands, particularly …


Determining Soil Erosion With Varying Corn Stover Cover Factors, Nicole K. Koeninger Jan 2015

Determining Soil Erosion With Varying Corn Stover Cover Factors, Nicole K. Koeninger

Theses and Dissertations--Biosystems and Agricultural Engineering

Since the Dust Bowl, conservation agriculture has become a common practice globally. Because of the rising interest in the use of corn biomass as a feedstock for biofuel production, the effects of corn stover removal on soil erosion were explored. It was hypothesized that selective harvesting strategies would impact soil erosion differently across a variety of slopes. Soil erosion boxes were constructed, and a rainfall simulator with an intensity of 30 mm hr-1 for 46 min was used to create runoff from slopes of 1, 5, and 10% and three cover factor treatments (no removal and two simulated corn …


Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines Jan 2013

Using Gis To Delineate Headwater Stream Origins In The Appalachian Coal-Belt Region Of Kentucky, Jonathan A. Villines

Theses and Dissertations--Biosystems and Agricultural Engineering

Human activity such as surface mining can have substantial impacts on the natural environment. Performing a Cumulative Hydrologic Impact Assessment (CHIA) of such impacts on surface water systems requires knowing the location and extent of these impacted streams. The Jurisdictional Determination (JD) of a stream’s protected status under the Clean Water Act (CWA) involves locating and classifying streams according to their flow regime: ephemeral, intermittent, or perennial. Due to their often remote locations and small size, taking a field inventory of headwater streams for surface mining permit applications or permit reviews is challenging. A means of estimating headwater stream location …


Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine Jan 2013

Hydrologic Characterization Of A Rain Garden Mitigating Stormwater Runoff From A Commercial Area, John T. Mcmaine

Theses and Dissertations--Biosystems and Agricultural Engineering

Impervious surfaces such as roads, sidewalks, and roofs increase the volume of runoff generated in a watershed. Traditional stormwater management techniques emphasize conveyance of runoff away from impervious surfaces in order to reduce flooding. Rain gardens are becoming popular as a different means to manage stormwater in such a way that runoff is captured and infiltrated onsite rather than conveyed offsite. A stormwater management system consisting of a rainwater harvest system, rain garden, and infiltration chamber was built at the Coca-Cola Refreshments USA, Inc. distribution center in Lexington, Kentucky during the fall of 2011. Precipitation, inflow, and water level were …