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Civil and Environmental Engineering

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University of Central Florida

Theses/Dissertations

Ferrate

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Evaluation Of Oxidized Media Filtration Processes For The Treatment Of Hydrogen Sulfide In Groundwater, Vito Trupiano Jan 2010

Evaluation Of Oxidized Media Filtration Processes For The Treatment Of Hydrogen Sulfide In Groundwater, Vito Trupiano

Electronic Theses and Dissertations

This study evaluated alternative sulfide treatment processes for potable water systems that rely on groundwater supplies. Research for this study was conducted at the Imperial Lakes (IL) and Turner Road (TR) water treatment plants (WTPs) in Polk County, Florida. These WTPs are in the process of refurbishment and expansion, and will require the installation of a new groundwater well. The IL and TR WTPs both rely upon groundwater sources that contain total sulfide at concentrations ranging from 1.4 to 2.6 mg/L. Sulfide is a concern because if left untreated it can impact finished water quality, corrosivity, create undesirable taste and …


Comparison Of The Effectiveness Of Alternative Ferrate (Vi) Synthesis Formulas As Disinfectants For Wastewater And River Water, Rachelle Ginart Jan 2008

Comparison Of The Effectiveness Of Alternative Ferrate (Vi) Synthesis Formulas As Disinfectants For Wastewater And River Water, Rachelle Ginart

Electronic Theses and Dissertations

Ferrate (VI) has been studied as an alternative chemical to disinfect water and wastewater in recent years. The disinfection effectiveness of two different wet oxidation ferrate (VI) synthesis formulas in wastewater and Econlockhatchee River water was evaluated. Ferrate (VI) is synthesized by addition of ferric chloride to a mixture of sodium hydroxide and calcium hypochlorite (refer to U.S. Patent 6,790,429). One ferrate (VI) synthesis formula uses below the stoichiometric requirement of hypochlorite (Low Chlorine Formula) while the other ferrate (VI) synthesis formula uses more than the stoichiometric requirement of hypochlorite (Standard Chlorine Formula). For applications requiring low chlorine residual effluent …


Removal Of 2, 4-Dinitrophenol By Ferrate, Gianna Cooley Jan 2008

Removal Of 2, 4-Dinitrophenol By Ferrate, Gianna Cooley

Electronic Theses and Dissertations

Ferrate (molecular formula, FeVIO42-) has been studied increasingly since the 1970s as a disinfectant and coagulant for domestic wastewater and also as an oxidant for industrial wastewaters (Murmann and Roginson, 1974, Gilbert et al., 1978, Kazama, 1994, Jiang et al., 2002, and Sharmaet al., 2005). This research was performed to explore whether ferrate could possibly be used as chemical treatment for industrial wastewaters from plastic, chemical, dye, soap, and wood stain producing plants that contain 2, 4-Dinitrophenol (DNP). DNP is listed on the United States Environmental Protection Agency (EPA) Drinking Water Contaminant Candidate List (CCL). This list includes compounds which …


Comparison Of Thm Formation During Disinfection: Ferrate Versus Free Chlorine For Different Source Waters, Adhem Mukattash Jan 2007

Comparison Of Thm Formation During Disinfection: Ferrate Versus Free Chlorine For Different Source Waters, Adhem Mukattash

Electronic Theses and Dissertations

The objective of the study was to compare the trihalomethanes (THMs) produced from ferrate with hypochlorite and to determine how different the THM production would be for a given degree of disinfection (3 log reduction in Heterotrophic Plate Count (HPC)). Different water samples were collected from Lake Claire, Atlantic Ocean, and secondary effluent from an advanced wastewater treatment plant. THM formation was determined using a standard assay over 7 days at room temperature. In addition samples were tested for Total Coliform Escherichia coli (TC/E.coli), and heterotrophic bacteria using HPC by spreadplating on R2A agar. Dissolved organic carbon (DOC) was measured …


A Non-Isolated Half Bridge Buck-Based Converter For Vrm Application And Small Signal Modeling Of A Non-Conventional Two Phase Bu, Majd Batarseh Jan 2006

A Non-Isolated Half Bridge Buck-Based Converter For Vrm Application And Small Signal Modeling Of A Non-Conventional Two Phase Bu, Majd Batarseh

Electronic Theses and Dissertations

This dissertation is about treatment of the nonbiodegradable organic content of landfill leachate by chemical oxidation combined with biological treatment. It is divided into three parts. In the first part, ferrate was compared to Fenton's reagent for the purpose of removing non-biodegradable organic compounds from mature leachate. Oxidation conditions (time, pH, and dose) were optimized to yield maximum organic removal using two leachate samples from 20 and 12-year old solid waste cells. Results from this research demonstrated that ferrate and Fenton's reagent had similar optimum pH ranges (3-5), but different organic removal capacities, ranging from 54 to 79 % of …


Removal Of Refractory Tkn From An Effluent Wastewater Using Sodium Ferrate, Lucia Lettie Jan 2006

Removal Of Refractory Tkn From An Effluent Wastewater Using Sodium Ferrate, Lucia Lettie

Electronic Theses and Dissertations

This research addresses refractory forms of nitrogen that, even with advanced biological nitrification-denitrification systems are not removed completely from domestic wastewater. TKN (Total Kjeldahl Nitrogen), ammonia plus organic nitrogen, is one of the forms to measure the levels of nitrogen present in effluent wastewaters. Ferrate, a strong oxidant, was used for the treatment of these nitrogen forms with the objective of producing nitrogen compounds that can be removed by subsequent biological processes. Bench-scale experiments were performed on effluent samples taken prior to chlorination from an Orlando, FL wastewater treatment facility, using a biological nutrient removal process. The samples were treated …


Dewatering Of Biosolids By Sodium Ferrate, Andrea Rios Jan 2004

Dewatering Of Biosolids By Sodium Ferrate, Andrea Rios

Electronic Theses and Dissertations

This study was conducted to evaluate the effectiveness of the liquid form of ferrate for dewatering of biosolids from wastewater treatment facilities. Two different ferrate products prepared using calcium hypochlorite and sodium hypochlorite were used. Samples of anaerobic digested sludge and waste activated sludge with solids content of 2.1% and 0.95 %, respectively were conditioned with both products to evaluate and compare their effectiveness. Centrifugation and filtration of the sludge after conditioning were used. For centrifugation the volume reduction and the turbidity of the supernatant after centrifugation were evaluated. For filtration, the Capillary Suction Time test was used. The optimum …