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Voltammetric Studies Of Metallofullerenes, Mark Anderson
Voltammetric Studies Of Metallofullerenes, Mark Anderson
Mark R. Anderson
No abstract is available at this time.
Voltammetry And Spectroelectrochemistry Of Metallofullerenes, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Voltammetry And Spectroelectrochemistry Of Metallofullerenes, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Mark R. Anderson
No abstract is currently available.
The Voltammetry Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
The Voltammetry Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Mark R. Anderson
No abstract is currently available.
The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
The Voltammetry Of Sc3@C82, Mark Anderson, Harry Dorn, Paul Burbank, Steven Stevenson, James Gibson
Mark R. Anderson
Many endohedral metallofullerenes have a C82 cage surrounding the metals, even though the normal arc-vaporization method of fullerene preparation does not generate C82 in significant abundance.1-10Manolopous et al.11-13attribute the low abundance of empty-cage C82 to the unfavorable electron configuration of this species. Consequently, the prevalence of C82 in metallofullerenes may be the result of an electron transfer from the encapsulated metal atoms to the fullerene cage.10-13 The extent of this charge transfer also contributes to the properties (e.g. catalytic, superconductive, nonlinear optical, and ferromagnetic) that are attributed to the endohedral metallofullerenes.14,15Because of the importance of the charge transfer reaction, characterization …
Voltammetric Studies Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Voltammetric Studies Of Mn@C82, Mark Anderson, Harry Dorn, Paul Burbank, James Gibson
Mark R. Anderson
The voltammetry for a series of related endohedral metallofullerenes is reported. It is found that as additional metal atoms are inserted into the fullerene cage, the first reduction of the metallofullerenes shifts to more negative potentials. This is consistent with more charge being transferred to the fullerene cage from the additional metal atom; however, the magnitude of the shift is much smaller than expected.