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Lignin Transformation And Characterization Of Pyrolytic Products, Eric Amo Boakye Jan 2017

Lignin Transformation And Characterization Of Pyrolytic Products, Eric Amo Boakye

Electronic Theses and Dissertations

Lignocellulosic materials derived from plants have the ability to serve as feedstocks in place of depleting petroleum and coal for production of fuels and chemicals. Lignin forms about 30% of lignocellulosic material, and is the second most abundant non-fossil organic carbon source in the biosphere. However, it is often treated as waste or, in some instances, burned to supply energy. Developing an efficient and environmentally benign method to convert lignin to high value-added aromatic monomers (e.g., guaiacol, vanillin, acetovanillone, and eugenol) for synthesis of polymers is of interest. Mineral bases, such as NaOH and CsOH, or supported-metal catalysts (Pt, Ru, …


Relationship Of The Fractal And Chemical Characteristics Of Self-Assembled Natural Organic Matter, Dennis K. Gibson Jan 2017

Relationship Of The Fractal And Chemical Characteristics Of Self-Assembled Natural Organic Matter, Dennis K. Gibson

Electronic Theses and Dissertations

Natural Organic Matter (NOM) is a heterogeneous mixture formed by the degradation of organic substances during early diagenesis in surficial environments. It has been shown that the interaction of the components that comprise this mixture has a significant impact on its microbial mineralization to CO2. The extent of NOM selfassembly is emerging as an important factor in understanding its role in the global geochemical carbon cycle, and it is beginning to appear that it may be more important than the chemical composition of a sample. The overall goal of this research is to establish NOM’s self-assembled “architecture” and …