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An Investigation Of Metallic Rhenium, Rhenium Dioxide And Rhenium Chlorides As Catalysts In The Hydrogenation Of Certain Organic Substrates, Walter William Brown
An Investigation Of Metallic Rhenium, Rhenium Dioxide And Rhenium Chlorides As Catalysts In The Hydrogenation Of Certain Organic Substrates, Walter William Brown
Theses and Dissertations
The purpose of the present investigation was to examine the various analytical methods to ascertain the suitability of the methods for our use in determining the amount of rhenium used in our catalysts, and, if necessary devise a new method. Also, several catalysts were to be prepared and used in hydrogenation or organic compounds. Evaluation of the catalytic activity of each catalyst was to be made by using them with various selected organic substrates.
Rhenium Trioxide, Rhenium Heptoxide And Rehnium Trichloride As Hydrogenation Catalysts, William J. Bartley
Rhenium Trioxide, Rhenium Heptoxide And Rehnium Trichloride As Hydrogenation Catalysts, William J. Bartley
Theses and Dissertations
The purpose of this study was to characterize the catalytic activity of rhenium trioxide and rhenium trichloride as hydrogenation catalysts. Work was also undertaken to further study the catalytic properties of rhenium heptoxide. The activity of this latter compound had received some study in a previous project. A complete review of the literature has been made on the organic and inorganic chemistry of rhenium trioxide and rhenium trichloride. A survey of the literature on catalytic hydrogenation and the chemistry of rhenium heptoxide has also been included. Rhenium trioxide was prepared by three similar methods. The first two involved the formation …
Rhenium Catalysis I. Hydrogenation And Hydroformylation Using Rhenium Carbonyl Compounds ; Ii. Hydrogenation Using Catalysts Obtained From The Reduction Of Perrhenates With Metals In Aqueous Solution, Terry G. Selin
Theses and Dissertations
The purpose of this work was to investigate the catalytic activity in both hydrogenation and hydroformylation reactions of rhenium preparations which have not been previously characterized. Rhenium pentacarbonyl was prepared in good yield from rhenium heptoxide and carbon monoxide. The optimum conditions for preparation were 25 hours per gram of dry rhenium heptoxide at 250° under 3000 psig. (initial) of carbon monoxide. Rhenium chloropentacarbonyl was prepared in 62% yield from potassium chlororhenite and carbon monoxide at high temperatures and pressures. The iodopentacarbonyl was prepared in 29% yield from potassium perrhenate, methyl iodide, and carbon monoxide. The preparation of rhenium hydrocarbonyl …
The Preparation And Catalytic Properties Of Rhenium Blacks Obtained By Reduction Of Re(Vii) In Anhydrous Ammonia And Amines With Alkali Metals, David William Seegmiller
The Preparation And Catalytic Properties Of Rhenium Blacks Obtained By Reduction Of Re(Vii) In Anhydrous Ammonia And Amines With Alkali Metals, David William Seegmiller
Theses and Dissertations
The purpose of the investigation was to determine the catalytic activity of rhenium blacks obtained by reduction of rhenium salts in alkali metal-ammonia or amine systems. A review is presented on the chemical, physical and catalytic properties of rhenium, and on the rhenide ion, on the nature of the alkali metal-liquid ammonia system, and the reduction of metallic salts therein. The first reduction system studied was that obtained by dissolving sodium in liquid ammonia. The salts reduced in this system were KReO_4, Re_2O_7 and NH_4ReO_4. The reduction of KReO_4 was unsuccessful, and the heptoxide was difficult to handle. The product …
Colorimetric Determination Of Rhenium In Ores, Clair Winston Rogers
Colorimetric Determination Of Rhenium In Ores, Clair Winston Rogers
Theses and Dissertations
The problem of colorimetrically determining rhenium in the presence of molybdenum, copper, iron, sulphur, and rare earth elements with the use of dimethylglyoxime as the complexing compound was accomplished by the method reported here-in. The interfering elements were eliminated either as gaseous oxides and sulfides or were precipitated from a highly basic solution by means of a strong alkaline fusion of equal weights of sodium hydroxide and sodium peroxide, and the ore sample containing rhenium. The fusion product was dissolved in water, the solution boiled with a slight excess of sodium peroxide, and the hydroxide of all the interfering ions …