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Chemistry

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Electronic Theses and Dissertations

2008

Environmental

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Determination Of The Degradation Mechanism For Polychlorinated Biphenyl Congeners Using Mechanically Alloyed Magnesium/Palladium, Robert Devor Jan 2008

Determination Of The Degradation Mechanism For Polychlorinated Biphenyl Congeners Using Mechanically Alloyed Magnesium/Palladium, Robert Devor

Electronic Theses and Dissertations

Polychlorinated biphenyls are a ubiquitous environmental contaminant that can be found today throughout the world in soils and sediments, lakes and rivers, and flora and fauna. PCBs have percolated throughout the food chain, so that almost every human being has a detectable amount of the contaminant within their blood stream. Existing remediation methods include incineration, dredging and landfilling, and microbial degradation, but all of these methods have drawbacks that limit their effectiveness as treatment options. Recently, the use of zero-valent metals as a means of reductive dechlorination has been explored. Using a combination of zero-valent magnesium and catalytic palladium, a …