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Chemistry

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University of Central Florida

Theses/Dissertations

Optical data storage

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Investigating New Guaiazulenes And Diketopyrropyrroles For Photonic Applications, Ebrahim Ghazvini Zadeh Jan 2015

Investigating New Guaiazulenes And Diketopyrropyrroles For Photonic Applications, Ebrahim Ghazvini Zadeh

Electronic Theses and Dissertations

?-Conjugated systems have been the focus of study in recent years in order to understand their charge transport and optical properties for use in organic electronic devices, fluorescence bioimaging, sensors, and 3D optical data storage (ODS), among others. As a result, several molecular building blocks have been designed, allowing new frontiers to be realized. While various successful building blocks have been fine-tuned at both the electronic and molecular structure level to provide advanced photophysical and optoelectronic characteristics, the azulene framework has been under-appreciated despite its unique electronic and optical properties. Among several attributes, azulenes are vibrant blue naturally occurring hydrocarbons …


Synthesis Of Novel Fluorene-Based Two-Photon Absorbing Molecules And Their Applications In Optical Data Storage, Microfabricatio, Ciceron Yanez Jan 2009

Synthesis Of Novel Fluorene-Based Two-Photon Absorbing Molecules And Their Applications In Optical Data Storage, Microfabricatio, Ciceron Yanez

Electronic Theses and Dissertations

Two-photon absorption (2PA) has been used for a number of scientific and technological applications, exploiting the fact that the 2PA probability is directly proportional to the square of the incident light intensity (while one-photon absorption bears a linear relation to the incident light intensity). This intrinsic property of 2PA leads to 3D spatial localization, important in fields such as optical data storage, fluorescence microscopy, and 3D microfabrication. The spatial confinement that 2PA enables has been used to induce photochemical and photophysical events in increasingly smaller volumes and allowed nonlinear, 2PA-based, technologies to reach sub-diffraction limit resolutions. The primary focus of …


Two-Photon 3d Optical Data Storage Via Fluorescence Modulation Of Fluorene Dyes By Photochromic Diarylethenes, Claudia Corredor Jan 2007

Two-Photon 3d Optical Data Storage Via Fluorescence Modulation Of Fluorene Dyes By Photochromic Diarylethenes, Claudia Corredor

Electronic Theses and Dissertations

Three-dimensional (3D) optical data storage based on two-photon processes provides highly confined excitation in a recording medium and a mechanism for writing and reading data with less cross talk between multiple memory layers, due to the quadratic dependence of two photon absorption (2PA) on the incident light intensity. The capacity for highly confined excitation and intrinsic 3D resolution affords immense information storage capacity (up to 1012 bits/cm3). Recently, the use of photochromic materials for 3D memory has received intense interest because of several major advantages over current optical systems, including their erasable/rewritable capability, high resolution, and high sensitivity. This work …