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Detection Of Boronic Acids Through Excited-State Intramolecular Proton-Transfer Fluorescence, Matthew R. Aronoff, Brett Vanveller, Ronald T. Raines
Detection Of Boronic Acids Through Excited-State Intramolecular Proton-Transfer Fluorescence, Matthew R. Aronoff, Brett Vanveller, Ronald T. Raines
Brett VanVeller
Boronic acids are versatile reagents for the chemical synthesis of organic molecules. They and other boron-containing compounds can be detected readily by the interruption of the excited-state intramolecular proton transfer (ESIPT) of 10-hydroxybenzo[h]quinolone. This method is highly sensitive and selective, and useful for monitoring synthetic reactions and detecting boron-containing compounds on a solid support.
The Synthesis Of Azaperylene-9,10-Dicarboximides, Brett Vanveller, Kojl Miki, Timorthy M. Swager
The Synthesis Of Azaperylene-9,10-Dicarboximides, Brett Vanveller, Kojl Miki, Timorthy M. Swager
Brett VanVeller
The efficient synthesis of a hydrophilic monomer bearing a three-dimensional noncompliant array of hydroxyl groups is described that prevents water-driven excimer features of hydrophobic poly(p-phenylene ethynylene) backbones. Sensitivity of the polymer to 3-nitrotyrosine is also discussesd.
Ionic Liquids In Analytical Chemistry, Jared L. Anderson, Daniel W. Armstrong, Guor-Tzo Wei
Ionic Liquids In Analytical Chemistry, Jared L. Anderson, Daniel W. Armstrong, Guor-Tzo Wei
Jared L. Anderson
Room-temperature ionic liquids (RTILs), also known as liquid organic, molten, or fused salts, are a class of nonmolecular ionic solvents with low melting points. The accepted definition of an RTIL is any salt that has a melting point lower than ambient temperature (1). However, “ionic liquid” (IL) is often applied to any compound that has a melting point <100 °C. Most common RTILs are composed of unsymmetrically substituted nitrogen-containing cations (e.g., imidazole, pyrrolidine, pyridine) with inorganic anions (e.g., Cl–, PF6 –, BF4 –). ILs are also interesting because of their other useful and intriguing physicochemical properties. Wilkes et al. first reported ambient-temperature ILs based on the 1-alkyl-3-methylimidazolium cation in 1982 (2). Since then, many ILs containing a variety of cations and anions of different sizes have been synthesized to provide specific characteristics.