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Chemistry

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Clemson University

Theses/Dissertations

2015

Garnets

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Towards A Greater Understanding Of Hydrothermally Grown Garnets And Sesquioxide Crystals For Laser Applications, Cheryl Moore Dec 2015

Towards A Greater Understanding Of Hydrothermally Grown Garnets And Sesquioxide Crystals For Laser Applications, Cheryl Moore

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ABSTRACT The hydrothermal method of crystal growth offers many benefits over traditional melt-based techniques such as lower temperature requirements relieving detrimental high temperature effects such as stress fracturing and a closed-environment, which limits impurities. The continued study of this type of growth including hydrothermal epitaxy is crucial in our world of constant miniaturization. Presented in this thesis is the hydrothermal growth of crystals of LuAG and Lu2O3 doped with a variety of dopants. Their room-temperature and cryogenic absorption spectra are also presented. Much like Nature uses heat, pressure, water and a nutrient-rich feedstock we have used this hydrothermal technique to …