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Chemical Engineering

Theses/Dissertations

2003

Bridging

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Rotational Molding Of Acrylonitrile-Butadiene-Styrene Polymers And Blends, Mark Grant Spencer Dec 2003

Rotational Molding Of Acrylonitrile-Butadiene-Styrene Polymers And Blends, Mark Grant Spencer

Theses and Dissertations

The development of acrylonitrile-butadiene-styrene (ABS) resins for use in rotational molding would provide a medium performance material, thus opening doors to new markets for the rotational molding industry. Unfortunately, ABS resins have shown serious problems during the rotational molding process, namely discoloration, bridging, and poor impact strength. It is believed that these effects are due to degradation of the carbon-carbon double bond in the butadiene, through attack by either oxygen or heat. Previous efforts have shown some success in addressing these issues. However, additional improvements are necessary to make ABS resins commercially viable to rotational molders. This study, fourth in …