Digital Commons Network^™

Thermal Decomposition Of Chlorobenzene Reaction With Hydrogen And Oxygen Mixture In An Atmosphere, Chun-Chen Yang

Theses

The thermal reactions of chlorobenzene in hydrogen and oxygen mixtures were studied in tubular flow reactors at 1 atmosphere total pressure. Experiments were carried out in flow reactors of varied diameter for determining effects of different surface to volume ratios. Residence times ranged from 0.03 to 2.5 seconds and temperature was varied over a range of 560 - 660 °C. The 02/H2 ratios ranged from 1% to 5%.

It was found that the conversion of chlorobenzene in hydrogen and oxygen mixtures increased with both temperature and residence time. The oxidation of chlorobenzene also occurred more rapidly when oxygen concentraction was …

Agitation Requirements For Complete Drawdown Of Floating Solids In Stirred Tanks, Joseph Philemon Mmbaga

Theses

The agitation requirements for complete drawdown of floating solids in mechanically agitated tank vessels has been studied both theoretically and experimentally.

A semi-theoretical equation has been derived on the basis of Kolmogoroff's theory of isotropic turbulence to determine the minimum impeller speed required for drawdown. The equation contains one adjustable parameter which has been found to be a function of the impeller type and position in the tank vessel.

The equation was tested using various vessels and impeller configurations. The solid phase consisted of high density polyethylene (density = 897kg/m³), low density polyethylene (density = 840kg/m³) …

Process Modelling Of The Nitration Of Toluene, Nitin K. Shah

Theses

The thesis on the process modelling of the nitration process focuses specifically on the product separation of the nitrated aromatic material from the reactor and - wash section of the process. Included in the text is an overview of the main process steps associated with the production of para and ortho-nitrotoluene. The critical issues concerning the reaction of nitric acid and toluene were summerized, and resulted in this subject being deferred for future work.

The separation of the isomers into pure components is an important. part of the MNT process because of the close high boiling points of the isomeric …

Protein Separation With Mathematical Modeling For Chromatographic Operation, Hsien-Chih Ma

Dissertations

We have performed experiments and derived mathematical models for packed bed columns used for liquid phase chromatographic separations of proteins with impulse input of feed solutions. These models can now be used to describe the relationships between the elution characteristics (peak height, peak position, and shapes) and the operating conditions (flow rate and buffer conditions) of ion exchange and gel permeation column chromatography for protein separations.

The surface adsorption model was discussed relative to the nature of the mobile and stationary phases in ion exchange column chromatography for two distinct cases: with and without pore diffusion. For large solute molecules, …

Quantification Of Refining Actions, Hari R. Goyal

Masters Theses

The repeated action of compression-decompression pulses on a wet web of fiber, created by dropping a weight from a height, loosens the internal structure of the fiber. The impaction of fiber did not cause any change in average weighted fiber length, fine content or Canadian Standard Freeness. The sheet made from these fibers showed an increase in tensile strength with increased number of impacts or impact intensity.

In a blend of impacted fibers (internally fibrillated), abraded fibers (externally fibrillated) and fines (fibers shorter than 0.23 mm and created by prolonged beating in a Valley beater), fines were found to be …

Heat Transfer Model And Computer Program For A Direct-Fired Rotary Kiln, Steven J. Kirslis

Masters Theses

An improved heat transfer model has been developed for a direct-fired rotary kiln. The model can be used to verify Kiln design, to optimize operating conditions, to predict the temperature history of the solids, and to evaluate if local areas of the kiln will be overheated. The treatment of radiant heat transfer was based on the Reflection Method developed by Succec and applied by Gorog, and was extended to account for radiation from a flame. Some elements of the Resistive Network Method and Zone Method were incorporated in the model. This method results in a more straightforward and flexible treatment …

Biodegradation Of Benzene And A Btx Mixture Using Immobilized Activated Sludge, Mayur Padamshi Lodaya

Dissertations

Aerobic biodegradation of benzene was studied using activated sludge immobilized in calcium alginate (immobilization by entrapment), and also attached to a silica based catalyst.support (immobilization by attachment). Hydrogen peroxide was used as a source of dissolved oxygen to eliminate physical removal of benzene due to aeration. Abiotic losses of benzene were accounted for.

A recirculation reactor, run in both batch and continuous feed mode, was used to determine the kinetic parameters. The system response was examined by tollowing changes in benzene concentration, flow rate, and biomass loading. The system was modeled mathematically and the kinetic parameters were determined.

Biological removal …

Thermotropic Liquid Crystalline Polyesters Based On The Monomer Of Poly(Ethylene Terephthalate), Satish Baliga

Dissertations

A series of thermotropic liquid crystalline polyesters were synthesized, based on Bis-hydroxyethyl terephthalate (BHET), para-acetoxybenzoic acid (PAB) and terephthalic acid (TA). Structural studies of these aromatic polyesters using Nuclear Magnetic Resonance (NMR), Infrared Spectroscopy (IR) and X-ray diffraction techniques indicated the existence of substantial amounts of rigid -PAB-PAB- linkages within the mesogenic backbone. Optical study of their melts using Polarizing Microscopy indicated a "threaded" microstructure typical of a nematic mesophase. Morphological rearrangements were found to occur at higher temperatures as was evident from a two-phase structure, one phase speculated to be rich in flexible Poly(ethylene Terephthalate) (PET) segments and the …

Kinetic Study On Pyrolysis Of C6h5cl And M-C6h4cl2 Diluted In H2 : Detailed Reaction Kinetics And Thermodynamic Property Estimation Techniques, Edward Robert Ritter

Dissertations

Thermal reaction studies of dilute mixtures (0.37%) of C6H5Cl in hydrogen and m-C6H4C12 (0.4%) in hydrogen have been performed in tubular flow reactors at various surface to volume ratios, and 1 atm total pressure. Residence times range from 0.02 to 2.5 seconds,with temperatures between 1050 to 1275 K. HCl, C₆H₅Cl, C₆H₆, and carbon solids (C(s)) are observed as the major products; minor products include methane, cyclopentadiene, toluene, naphthalene and biphenyls. Pyrolysis in helium yields significantly less conversion, but more C(s) for similar residence times.

A detailed chemical mechanism is developed to describe …

A Study Of The Effect Of Some Inhibitors On The Corrosion Rates Of Austenitic Stainless Steels In Sulfuric Acid, Shang-Yinn Chiou

Theses

Four sulfur-containing and three nitrogen-containing organic compounds have been tested as inhibitors for four different austenitic stainless steels-SS304, S5316, SS317L, and SS41O-in 10-50 weight% sulfuric acid solutions respectively. Results confirmed that the sulfur-containing compounds were more effective than the nitrogen-containing compounds. The effect of sodium iodide additions on the behaviours of two of the nitrogen-containing compounds was also studied. The synergistic effect caused by the 1 ion was essential for nitrogen-containing compounds as inhibitors in sulfuric acid solution.

Reactor Design For Hazardous Waste Treatment Using Immobilized Phanerochaete Chrysosporium, Ikram Ul Haq

Theses

The degradation of 2-Chlorophenol by Phanerochaete chrysosporium, a white rot fungus, was studied in three different reactor configurations, namely a batch reactor, a chemostatic reactor with the fungus immobilized on a silica based porous biocatalyst, and a packed bed reactor utilizing balsa wood chips as packing.

Preliminary experiments indicated that the use of porous solid support improved the degradation rate in batch reactor and chemostatic reactor. However, the packed bed configuration was found to be superior, and was studied in greater detail. The apparent Michaelis-Menten kinetic constants were obtained for the packed bed reactor.

Prediction And Correlation Of Liquid-Liquid Equilibria, Jose Simonetty Jr.

Theses

The NRTL, LEMF, and UNIQUAC models are used in the prediction and correlation of liquid-liquid equilibrium data for ten type I systems. The results indicate that best predictions are obtained with the LEMF equation, with an overall average absolute percentage error in distribution coefficients of 19.5 as compared to 23.0 and 24.7 with the NRTL and UNIQUAC equations, respectively. Good correlation of liquid-liquid equilibrium data alone is obtained with all three models; the LEMF equation is slightly better with an overall average absolute percentage error in distribution coefficients of 5.5 as compared to 6.7 and 5.9 for the NRTL and …

Mathematical Model Of A Continuous Sterilization System For Fermentation Media Containing Suspended Solids, Mark A. Leskowicz

Theses

A mathematical model has been developed for a continuous sterilization system where the role of suspended solids on the overall degree of sterilization achieved is taken into account. Evaluation of a "typical" commercial continuous sterilization system showed the role of suspended solids to have little effect on the overall sterilization obtained. For continuous sterilization systems operating in a total residence time of less than one minute, the role of solids may become important and should be evaluated.

Recirculation Flow Bioreactor For The Synthesis Of Nitroxide And N-Oxide Pharmaceuticals, Douglas Lischick

Theses

An investigation of the properties of calcium alginate immobilized hog liver microsomes, rich in FAD-containing mixed function oxidase, was performed. Studies involving catalyst storage, immobilization of cofactors within the matrix, and alginate gel concentration were performed using a 1.8 ml mixed flow micro assay reactor. A recirculation flow reactor was designed and used for the biochemical production of 2,2,4,4-tetramethyl-1,3-oxazolidine-l-oxyl, a potentially useful MRI contrast agent.

The activity of the immobilized microsomes was found to increase over time when stored in CaCl₂ or in buffer at 4-8°C. The increase in activity is a result of the removal of inherent inhibitors …

Estimation Of Thermodynamic Properties Of Petroleum Fractions To Supplement The Aspen Simulator, Steven E. Sund

Theses

The objective of this study was to develop a method of estimating hydrocarbon pseudocomponent data in a format that is consistent with the ASPEN simulator. Although algorithms exist to estimate the pseudocomponent properties, no comprehensive program exists for the public version of ASPEN. A computer program was developed which will take a minimum of input data and can generate the necessary pure component properties for an ASPEN simulation. The program is meant to complement the ASPEN simulator, so the input is similar to ASPEN's input. The output can be incorporated directly into an ASPEN input or can be of the …

Application Of Microwave Energy To Remediation Of Soils Contaminated With Chromium, Chih-Ju Jou

Theses

A process based upon microwave treatment has been developed to render soil non-hazardous after that soil had been classified as hazardous due to heavy metal contamination. It has been applied to chromium-contaminated soil. The object of the present regulations is to prevent damage to water supplies as a result of the leaching of heavy metal ions from the soils. This object is expressed in the standard test for leaching, namely, the EPA EP Leachate test. This process can be used to immobilize metal ions sufficiently to meet the aforementioned standard. The present standard is based upon acid leaching, and not …

A Study Of Volatile Organic Compound Emissions In The Ambient Air Of A Sanitary Landfill In Richard W. Dekorte State Park, New Jersey, Minsen Gao

Theses

A study was made of 15 volatile organic compounds (VOCs) in the ambient air emissions of a sanitary landfill located at Richard W. DeKorte Park, Lyndhurst, New Jersey. The samples were collected from July 1986 to September 1987 at 10 designated landfill sites over the selected time period from 4 to 24 hours by drawing the air to be analyzed through a Tenax trap. An average 10 to 15 liters of air sample was collected each time. Sample analysis is done on a Varian Gas Chromatograph (GC) combined with a Tekmar Thermal Desorber. A standard gas mixture of the 15 …

Ph Parametric Pumping : An Examination Of Different Feed Locations For A Two And Three Column Process With The Same Flow Patterns And Ph Distribution, Roberta Rosty

Theses

PH parametric pumping is used to separate protein mixtures of hemoglobin and Albumin.

In this thesis, modifications to a two-column process, where the fluid stage flow pattern and the pH distributions were constant, were explored. These modifications consisted of: changes in the feed stream inlet and outlet locations, changes in the amount of feed itself, and an addition of another column and reservoir to the original two-column process. The results were obtained through computer simulation.

Results indicate that the batch or no-feed two and three column processes yield better separations of the two proteins than the same processes with feed …

A Computer Program On The Economics Of Collection And Sortation Of Recyclable Materials In Municipal Solid Wastes, Ara Nigogos Kahyaoglu

Theses

The first version of the economic of recyclable materials in municipal solid waste analysis program was developed in interpretive BASIC by Rutgers the State University of New Jersey. Since BASIC is a line interpretative language several restrictions were encountered, the major one being the language size restriction.

The first objective was to obtain a truly portable program that would not be dependent on specific compilers and operating systems. The second objective was to generate a program that had the capability for expansion.

The C language was used over other high level languages such as PASCAL and FORTRAN because it had …

Thermal Decomposition Of 1,1,1-Thrichloroethane-Methane-Oxygen Mixture In Tubular Flow Reactor, Yo-Ping Wu

Theses

The thermal decomposition of 1,1,1-trichloroethane in methane/oxygen mixtures and argon bath gas was carried out at 1 atmosphere total pressure in a tubular flow reactors. The thermal degradation of 1,1,1-trichloroethane and methane were analyzed systematically over temperature ranges from 500 to 800°C, with average residence times in the range of 0.05 to 2.5 seconds. Five reactants ratio sets in three different size flow reactors were studied.

It was found that the complete decay (99%) of the 1,1,1-trichloroethane at 1 second residence time occurs at about 600°C for all the reactants ratio sets. The major product for 1,1,1-trichloroethane decomposition are 1,1-dichloroethylene …

The Influence Of Aggregate Grading With Two Different Binders On Mechanical Strength Of Polymer Concrete, Pei-Yuan Gao

Theses

The scope of this research is to study the influence of grading of the aggregate on the mixing design and the strength of polymer concrete .

Also, the curing conditions, the modification of polymer and the application of coupling agent were investigated.

Based on the experimental results, two numerical methods were developed to be used in combining the aggregates to obtain the desired specific surface area and the grading of the aggregate.

A computer program was developed for one of the methods to give all the possible compositions of the aggregate.

Theoretical explanation is offered and a numerical example is …

Thermodynamic And Leaching Studies Of Various Systems, Satya D. Rami

Theses

The group contribution approach is a reliable and fast method for the prediction of liquid phase activity coefficients in none lectrolyte, nonpolymeric mixtures at low to moderate pressures and temperatures between 300 and 425 K. It has become widely used in practical chemical engineering applications in cases where little or no relevant experimental information is available.

The two group contribution methods examined in the course of this work, are the Knox and & UNIFAC models. Group interaction parameters are evaluated for each of these models and results compared. Although the results for both models are similar when sufficient data are …

Dielectric And Kinetic Analysis Of Thermosetting Polyester Resin, Patricia Haverty Tully

Dissertations, Theses, and Masters Projects

No abstract provided.

Nonlinearity Parameters Of Polymers, Meng-Chou Wu

Dissertations, Theses, and Masters Projects

Three types of acoustic nonlinearity parameters for solids are discussed. The results of measurements of these parameters for three polymers--polymethyl methacrylate, Polystyrene, and polysulfone--are presented.;The author has developed a new technique, using piezoelectric transducers directly bonded to the specimens, which allows the measurements of fundamental and second harmonics generated in the solids, and thereby the determination of nonlinearity parameter {dollar}\beta\sb3{dollar}, which is the ratio of a linear combination of second- and third-order elastic coefficients to the second-order elastic coefficient.;The second nonlinearity parameter, B/A can be determined from the temperature and pressure derivatives of the sound velocity. We derive its exact …