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Synthesis And Enzymatic Resolution Of Amino Acid Esters In "Green" Solvents -- Ionic Liquids, Hua Zhao

Dissertations

Chiral separation has attracted tremendous attention in pharmaceutical and chemical fields, especially in the area of chiral drug development. Chiral amino acids are among the most important intermediates in the asymmetric synthesis of modem drugs. This research has developed an effective method for obtaining optically pure amino acids by enzymatic resolution using a "green" solvent, named an ionic liquid.

Ionic liquids, a new type of "green" solvents, have been used in many organic reactions and other chemical processes (such as liquid-liquid extraction) with improved performance. This is mainly due to their favorable properties for chemical applications, such as low vapor …

The Development Of H Homogeneous Nucleation Rate Model For Thermoplastic Foams Based On A Molecular Partition Function And Fickian Diffusion, Ronald G. Gabbard

Dissertations

An improved homogeneous nucleation rate model for thermoplastic foams has been developed. This model does not rely on experimentally determined parameters and only uses pure component physical property data and a binary diffusion coefficient. This model, like those derived from classical nucleation theory, is made up of two parts, one that determines the size of the energy barrier in the nucleation process and one that estimates the forward rate of the process. A statistical-mechanical approach was used to create an energy term that is based on a molecular partition function. In this approach, the bulk phase (polymer and blowing, agent …

Process Control Of A Laboratory Combustor Using Neural Networks, Thana Slanvetpan

Dissertations

Active feedback and feedforward-feedback control systems based on static-trained feedforward multi-layer-perceptron (FMLP) neural networks were designed and demonstrated, by experiment and simulation, for selected species from a laboratory two stage combustor. These virtual controllers functioned through a Visual Basic platform. A proportional neural network controller (PNNC) was developed for a monotonic control problem - the variation of outlet oxygen level with overall equivalence ratio (Φ₀). The FMLP neural network maps the control variable to the manipulated variable. This information is in turn transferred to a proportional controller, through the variable control bias value. The proposed feedback control methodology …

Application Of Chemical Kinetic Modeling To Improve Design And Performance Criteria For A Practical Incineration System, Charles A. Bass Jr.

Dissertations

In this study, detailed thermo-chemical kinetics with networked ideal reactor model were applied to simulate a practical combustion system -the Secondary Combustion Chamber (SCC) of the Rotary Kiln incineration Simulator (RKIS) at the EPA facility at Research Triangle Park, NC. The networked ideal model was developed using analysis of reactor geometry, temperature profile measurements, and SO₂ tracer data provided by EPA. A computer simulation of the networked model was developed using the CHEMKIN H library. A parallel effort considered the effects of non-ideal mixing on detailed thermo-kinetic, simulations. Specifically, an alternate approach was developed to solve the Partially Stirred …

Elementary, Pressure Dependent Model For Combustion Of C1, C2 And Nitrogen Containing Hydrocarbons : Operation Of A Pilot Scale Incinerator And Model Comparison, Chad Sheng

Dissertations

A 140000 BTU/hr pilot scale incinerator has been constructed, tested and run; and an online sampling train capable of taking in situ data has been established. The continuous on-line analytical instruments include a CO analyzer, an NO/NOx analyzer and an 02 analyzer. In addition, two gas chromatographs with flame ionization detector are used to determine CH4, C2H2 + C2H4 and total hydrocarbon concentrations. Typical operating conditions are at an average 02 concentration of 6 - 8 %. The NO concentration ranged from 100 - 200 ppm. Approximately I ppm of CH.4 is also present at steady state operations.

The kinetic …