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LSU Doctoral Dissertations

2009

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Photocatalytic Reaction In Monolithic Optical Fiber Reactor With Inverse Opal Catalyst, Maoming Ren Jan 2009

Photocatalytic Reaction In Monolithic Optical Fiber Reactor With Inverse Opal Catalyst, Maoming Ren

LSU Doctoral Dissertations

The development of photocatalytic reactor is essential for the successful application of heterogeneous semiconductor in environmental study, which has been shown to be photoactive and effective to oxidate organic pollutant and photoreduce CO2 to useful compounds. In this dissertation, a monolithic optical fiber reactor (MOFR) coated with inverse opal titania, which uses optical fibers as light-transmitting conductor and support of catalyst, was developed for both photodegradation and photoreduction. 1,2-dichlorobenzene, a volatile organic compound (VOC), was selected as the organic pollutant. This configuration of reactor and catalyst provides a high surface area, enhances mass transfer within the catalyst, manipulates photons transmission …