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Chemical Engineering

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University of Massachusetts Amherst

Theses/Dissertations

2022

Methylene Malonate

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Development Of Crosslinking Technologies For Waterborne & Powder Coatings, Mengfei Huang Feb 2022

Development Of Crosslinking Technologies For Waterborne & Powder Coatings, Mengfei Huang

Doctoral Dissertations

Waterborne coatings and powder coatings are fast-growing sectors of the world coating market due to their environmentally friendliness as they have low or zero volatile organic compounds (VOCs) emission. However, compared with solventborne coatings, significant limitations need to be overcome to enable their broad applications. My dissertation will discuss several novel crosslinking strategies for waterborne and powder coating that could enable curing on-demand at ambient conditions, with facile polymerization and easy processing, and ultimately, exhibit a high degree of crosslinking and excellent performance that is comparable to solventborne coatings. We introduced and demonstrated the anionic polymerization mechanism and the high …