Digital Commons Network^™

Mass Transfer To Droplets: Effect Of Non-Newtonian Continuous Phase., Hsin Chih Wu

Masters Theses

"Since non-Newtonian fluids are frequently encountered in the chemical and process industries, it is important that the transport processes which are commonly encountered be thoroughly investigated. Although studies of fluid mechanics and heat transfer with these fluids have been reported, virtually no work has been reported in the study of mass transfer. This is particularly true of mass transfer in turbulent flow.

The purpose of this investigation is to study the liquid-liquid mass transfer phenomenon in turbulent flow associated with single droplets in non-Newtonian continuous phases. The results are compared with those obtained in Newtonian systems. The data obtained will …

The Prediction Of The Viscosity Of Multi-Component Non-Polar Gaseous Mixtures At Atmospheric Pressure., Gary D. Fehsenfeld

Masters Theses

"The applicability of the Strunk, Custead, and Stevenson method for predicting the viscosities of multicomponent, non-polar, gaseous mixtures vas investigated. The viscosities of 24 ternary and quaternary gaseous mixtures were experimentally determined, at 3 temperature levels, and compared with the corresponding calculated viscosities resulting from the prediction method. In addition, the published viscosities of 64 multicomponent mixtures were compared with the corresponding calculated viscosities.

Altogether, the viscosities of 136 multicomponent, non-polar, gaseous mixtures were compared. The mixtures contained from 3 to 7 components including 16 different gases in the temperature range from 5• to 1014 ° c, and at a …

The Anodic Dissolution Of Zinc In Nitrate Solution., Jo Lisle Reed

Masters Theses

"The increasing demand for protective metals as coatings and non-corrosive alloys has stimulated extensive research on the fundamental behavior of metals in corrosive media.

One of the problems still unsolved is the nature of the mechanism of the anodic dissolution of metals like zinc, magnesium, beryllium, cadmium, and aluminum in aqueous salt solutions. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometric data and the weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for the anodic dissolution of zinc …

A New Method For The Evaluation Of Metal Primers., Bhalchandra Dave

Masters Theses

"Corrosion is the destructive attack of metal by chemical or electrochemical reaction with its environment. Rusting is usually the term applied to the corrosion of iron-base alloys with formation of corrosion products consisting largely of hydrous ferric oxides. Non-ferrous metals therefore, corrode but do not rust. ^(l4) More than 40 per cent of the world's production of steel and iron is destroyed by rusting which costs about six billion dollars every year. In 1954 the American Petroleum Industry, Subcommittee on Corrosion, published a preliminary estimate that corrosion was costing 2 the petroleum refining industry between eleven and nineteen cents per …

The Indole Acetic Acid Oxidase Of Hygrophorus Conicus., Dilip N. Patel

Masters Theses

"The purpose of this investigation was to determine an assay method for measuring the activity of the indole acetic acid oxidase present in Hygrophorus conicus. This enzyme converts tryptamine or indole acetic acid (IAA) into oxindole acetic acid (OIAA).

An assay method for measuring the activity of the enzyme was developed based on the spectrophotometric measurement of tryptamine, IAA, and OIAA. Several other assay methods were tried. The colorimetric method of Gordon and Weber ^(l4) was found to be useful for a quantitative determination of IAA and was insensitive to OIAA. Paper chromatography proved to be useful as a qualitative …

A Study Of The Separation Of A Mixture Of Carbon Dioxide And Hydrogen By Means Of An Orifice., Larry Gene Bauer

Masters Theses

"The purpose of the investigation was an attempt to verify a statement made by Partridge in an effort to discover a new method of separating gaseous mixtures. Partridge stated that when a constant pressure is applied on two gases of different specific gravity, a larger volume of the l igl1ter gas is forced through the orifice. Orifices of 1.016, 0.319, and 0.222 millimeter in diameter were used in the course of the investigation.

It was found that with the apparatus used in the research endeavor, no separation of the mixture of hydrogen and carbon dioxide could be obtained"--Abstract, p. i

Correlation Of Chemical Structure And Distensibility Of Polyesters., Nitin Jhaverbhai Bhimani

Masters Theses

"Maleic anhydride and fumaric acid are important raw materials for the manufacture of unsaturated polyesters. Unsaturated polyesters are the esterification products of unsaturated dibasic acids and polyvalent alcohols, polymerized to a high molecular weight resin"--Introduction, p. 1

The Dissolution Of Deformed Magnesium In Sulfuric Acid., William J. Daniels

Masters Theses

"The negative difference effect exhibited by magnesium while anodically dissolving in saline solutions has been attributed in part by Kokoulina and Kabanov to the expulsion of univalent magnesium ions ^{1, 2}. Recent experimenters have discounted the concept of the anodic expulsion of uncommon valency ions and have explained both the positive and negative difference effects observed for magnesium in dilute acids on the basis of anodic polarization, film disruption, and disintegration of the magnesium anode, i.e. "chunk effect"^{3, 4}.

The purpose of this present investigation was to study the difference effect for deformed magnesium in a dilute …

The Removal Of Residual Organic Materials From Sewage Plant Effluents Using Continuous Foam Flotation., Ajab S. Malik

Masters Theses

"This investigation was conducted to determine the feasibility of using a continuous foam flotation process for the removal of soluble organic materials from sewage treatment plant effluents. All effluents contained alkyl benzene sulfonates (ABS), derived from synthetic detergents. The studies were conducted on a laboratory scale. The reduction in the chemical oxygen demand was used as a measure of the effectiveness of the removal of the organic materials. In addition, ABS determinations were employed to study the fate of the detergent.

A flotation cell, equipped with the means of controlling the air and liquid flow rates, was used. Air flow …

Design, Construction And Characterization Of A 10-Liter Batch Pilot Plant Fermentor., Sylvester Ogden

Masters Theses

"A 10-liter batch type pilot plant fermentor has been designed and constructed. The design incorporated most of the desirable features of previous designs reported in the literature.

The stainless steel fermentor has a multi-speed agitator and aeration rates as high as 15 cubic feet per hour. Temperature indicating, temperature controlling, pH measuring, and automatic foam controlling systems are included in the design.

Sulfite oxidation rates have been determined for the unit at 15 operating conditions. A maximum sulfite oxidation rate of 1060 millimoles of oxygen per liter per hour has been obtained.

Fermentation using a Torulopsis utilis yeast culture has …

The Anodic Dissolution Of Cadmium In Aqueous Solution, Yun-Chung Sun

Masters Theses

"The increasing importance of prevention of corrosion in industry has stimulated extensive studies on the fundamental behavior of metals in corrosive media.

The basic mechanism of the anodic dissolution of metals such as cadmium, magnesium, and zinc in salt solutions is not completely known. Several mechanisms have been proposed by different investigators, but evidence is still lacking to draw unquestionable conclusions to explain the discrepancies which often arise between coulometric data and weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for anodic dissolution of cadmium in various electrolytes and …

A Study Of The Phase Behavior Of Carbon Dioxide-Methane-Normal Decane Systems, Raja Audi Mansoor

Masters Theses

“The effect of carbon dioxide concentration, on solubility has been studied for several carbon dioxide-methane-n-decane systems. Experimental results were obtained using differential vaporization tests. Computational results were obtained using equilibrium constants.

The relation between solubility, bubble point pressure and solution carbon dioxide is presented. A ternary diagram showing the bubble point pressure behavior as a function of system composition is also presented”--Abstract, page ii.

Study Of Mass Transfer In Oscillating Droplets., Subhash Vishnu Gangal

Masters Theses

"The object of this investigation was to study the resistance to mass transfer inside single oscillating liquid droplets falling in a liquid medium. The following four systems were studied: (1) 3% acetic acid in nitrobenzene and water, (2) 25% acetic acid in nitrobenzene and water, (3) 3% acetic acid in nitrobenzene and glycerin in water, and (4) benzyl alcohol and water. The individual mass transfer coefficients were computed by using the Handlos and Baron relation and were compared with the experimentally determined dispersed phase mass transfer coefficients. The average absolute deviation of the observed values of dispersed phase mass transferred …