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Biofuels From Crop Residue Can Reduce Soil Carbon And Increase Co2 Emissions, Adam J. Liska, Haishun Yang, Maribeth Milner, Steve Goddard, Humberto Blanco-Canqui, Matthew P. Pelton, Xiao X. Fang, Haitao Zhu, Andrew E. Suyker Apr 2014

Biofuels From Crop Residue Can Reduce Soil Carbon And Increase Co2 Emissions, Adam J. Liska, Haishun Yang, Maribeth Milner, Steve Goddard, Humberto Blanco-Canqui, Matthew P. Pelton, Xiao X. Fang, Haitao Zhu, Andrew E. Suyker

Adam Liska Papers

Removal of corn residue for biofuels can decrease soil organic carbon(SOC) and increase CO2 emissions because residue C in biofuels is oxidized to CO2 at a faster rate than when added to soil. Net CO2 emissions from residue removal are not adequately characterized in biofuel life cycle assessment (LCA). Here we used a model to estimate CO2 emissions from corn residue removal across the US Corn Belt at 580 million geospatial cells. To test the SOC model, we compared estimated daily CO2 emissions from corn residue and soil with CO2 emissions measured using eddy covariance, …


Assessment Of Corn Stover Torrefaction On-Farm Biochar Production, Christina M. Gerometta Jan 2014

Assessment Of Corn Stover Torrefaction On-Farm Biochar Production, Christina M. Gerometta

Electronic Theses and Dissertations

Torrefaction is a thermochemical pretreatment process that is typically achieved by slowly heating biomass (<50°C/min) within the temperature range of 200 – 300°C under an inert atmosphere. This process yields a storable solid product with enhanced fuel characteristics that are influenced by the ligno-cellulosic composition of the original feedstock and the imposed torrefaction conditions (time and temperature). This study is an assessment of corn stover properties that are relevant for designing an on-farm torrefaction system. The first portion of this study compared the thermal decomposition behaviors of corn stover fractions (leaf, stalk, cob) to the respective ligno-cellulosic composition using thermo-gravimetric analysis. It was found that the thermal decomposition pattern correlates to the structure and ratio of ligno-cellulosic polymers and provides design guidelines for an on-farm torrefaction system capable of handling large quantities of mixed fraction stover. The second part of this study investigated the effects of torrefaction time and temperature on the mass and energy yield of mixed fraction corn stover using a 46.3 L batch style reactor. It was found that longer reaction times and higher temperatures were required to obtain mass and energy yields similar to those found using lab-scale reactors and finely milled samples. Non-uniform torrefaction occurred between fractions due to chemical composition of each fraction and proximity to the heating elements.