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Immobilization Of Lead In Contaminated Firing Range Soil Using Biochar, Deok Hyun Moon, Jae-Woo Park, Yoon-Young Chang, Yong Sik Ok, Sang Soo Lee, Mahtab Ahmad, Agamemnon Koutsospyros, Jeong Hun Park, Kitae Baek Dec 2013

Immobilization Of Lead In Contaminated Firing Range Soil Using Biochar, Deok Hyun Moon, Jae-Woo Park, Yoon-Young Chang, Yong Sik Ok, Sang Soo Lee, Mahtab Ahmad, Agamemnon Koutsospyros, Jeong Hun Park, Kitae Baek

Civil Engineering Faculty Publications

Soybean stover-derived biochar was used to immobilize lead (Pb) in military firing range soil at a mass application rate of 0 to 20 wt.% and a curing period of 7 days. The toxicity characteristic leaching procedure (TCLP) was performed to evaluate the effectiveness of the treatment. The mechanism responsible for Pb immobilization in military firing range soil was evaluated by scanning electron microscopy-energy dispersive x-ray spectroscopy (SEM-EDX) and x-ray absorption fine structure (XAFS) spectroscopy analyses. The treatment results showed that TCLP Pb leachability decreased with increasing biochar content. A reduction of over 90 % in Pb leachability was achieved upon …


Biomass Gasification: An Alternative Solution To Animal Waste Management, Hanjing Wu May 2013

Biomass Gasification: An Alternative Solution To Animal Waste Management, Hanjing Wu

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

The overall goal of this research was to evaluate gasification of animal waste as an alternative manure management strategy, from the standpoints of syngas production and biochar application.

To meet the overall objective, the thermogravimetric characteristics of dairy manure, as a thermochemical conversion feedstock, were studied firstly. Then, gasification technology was applied to dairy manure and feedlot manure using a fluidized-bed laboratory-scale gasifier. In addition, biochar derived from the feedlot manure was examined for its effects on nutrient leaching as a soil amendment. Finally, a life cycle assessment was conducted to evaluate greenhouse gas emissions of two feedlot manure management …