Nanoscience and Nanotechnology Commons^™

Construction Of A Peridynamic Model For Viscous Flow, Jiangming Zhao, Adam Larios, Florin Bobaru Ph.D.

Mechanical & Materials Engineering Faculty Publications

We derive the Eulerian formulation for a peridynamic (PD) model of Newtonian viscous flow starting from fundamental principles: conservation of mass and momentum. This formulation is different from models for viscous flow that utilize the so-called “peridynamic differential operator” with the classical Navier- Stokes equations. We show that the classical continuity equation is a limiting case of the PD one, assuming certain smoothness conditions. The PD model for viscous flow is calibrated to the classical Navier-Stokes equations by enforcing linear consistency for the viscous stress term. Couette and Poiseuille flows, and incompressible fluid flow past a regular lattice of cylinders …

Visualization And Validation Of Twin Nucleation And Early-Stage Growth In Magnesium, Lin Jiang, Mingyu Gong, Jian Wang, Zhiliang Pan, Xin Wang, Dalong Zhang, Y. Morris Wang, Jim Ciston, Andrew M. Minor, Mingjie Xu, Xiaoqing Pan, Timothy J. Rupert, Subhash Mahajan, Enrique J. Lavernia, Irene J. Beyerlein, Julie M. Schoenung

Mechanical & Materials Engineering Faculty Publications

The abrupt occurrence of twinning when Mg is deformed leads to a highly anisotropic response, making it too unreliable for structural use and too unpredictable for observation. Here, we describe an in-situ transmission electron microscopy experiment on Mg crystals with strategically designed geometries for visualization of a long-proposed but unverified twinning mechanism. Combining with atomistic simulations and topological analysis, we conclude that twin nucleation occurs through a pure-shuffle mechanism that requires prismatic-basal transformations. Also, we verified a crystal geometry dependent twin growth mechanism, that is the early-stage growth associated with instability of plasticity flow, which can be dominated either by …

Recent Advances In Biosensors For Detection Of Covid-19 And Other Viruses, Shobhit K. Patel, Jaymit Surve, Juveriya Parmar, Kawsar Ahmed, Francis M. Bui, Fahad Ahmed Al-Zahrani

Mechanical & Materials Engineering Faculty Publications

This century has introduced very deadly, dangerous, and infectious diseases to humankind such as the influenza virus, Ebola virus, Zika virus, and the most infectious SARS-CoV-2 commonly known as COVID-19 and have caused epidemics and pandemics across the globe. For some of these diseases, proper medications, and vaccinations are missing and the early detection of these viruses will be critical to saving the patients. And even the vaccines are available for COVID-19, the new variants of COVID-19 such as Delta, and Omicron are spreading at large. The available virus detection techniques take a long time, are costly, and complex and …

Development Of A Model For Graphene Synthesis In Microwave Plasma-Assisted Reactors, Caleb Prindler

Electronic Theses and Dissertations

Graphene is a novel nanomaterial capable of revolutionizing technology in many sectors but is difficult to produce on a useful scale. To improve our understanding of graphene formation, a computational model has been developed to simulate graphene synthesis in a scalable microwave plasma reactor. Unlike earlier graphene growth models, this one uses a sectional method to solve the population balance model. A sensitivity analysis was performed to assess the impact of the individual process rates. The rates were adjusted by multiplying and dividing the base rates by a factor of 2. The process rates that were adjusted in this way …

Electro-Chemo-Mechanics Of The Interfaces In 2d-3d Heterostructure Electrodes, Vidushi Sharma

Dissertations

Unique heterostructure electrodes comprising two-dimensional (2D) materials and bulk three dimensional (3D) high-performance active electrodes are recently synthesized and experimentally tested for their electrochemical performance in metal-ion batteries. Such electrodes exhibit long cycle life while they also retain high-capacity inherent to the active electrode. The role of 2D material is to provide a supportive mesh that allows buffer space for volume expansions upon ion intercalation in the active material and establishes a continuous electronic contact. Therefore, the binding strength between both materials is crucial for the success of such electrodes. Furthermore, battery cycles may bring about phase transformations in the …

Seizure Detection Using Deep Learning, Information Theoretic Measures And Factor Graphs, Bahareh Salafian

Electronic Thesis and Dissertation Repository

Epilepsy is a common neurological disorder that disrupts normal electrical activity in the brain causing severe impact on patients’ daily lives. Accurate seizure detection based on long-term time-series electroencephalogram (EEG) signals has gained vital importance for epileptic seizure diagnosis. However, visual analysis of these recordings is a time-consuming task for neurologists. Therefore, the purpose of this thesis is to propose an automatic hybrid model-based /data-driven algorithm that exploits inter-channel and temporal correlations. Hence, we use mutual information (MI) estimator to compute correlation between EEG channels as spatial features and employ a carefully designed 1D convolutional neural network (CNN) to extract …

Smooth Muscle Cells Affect Differential Nanoparticle Accumulation In Disturbed Blood Flow-Induced Murine Atherosclerosis, Hunter Miller, Morgan A. Schake, Badrul Alam Bony, Evan T. Curtis, Conner C. Gee, Ian Mccue, Thomas J. Ripperda Jr., Yiannis S. Chatzizisis, Forrest Kievit, Ryan M. Pedrigi

Mechanical & Materials Engineering Faculty Publications

Atherosclerosis is a lipid-driven chronic inflammatory disease that leads to the formation of plaques in the inner lining of arteries. Plaques form over a range of phenotypes, the most severe of which is vulnerable to rupture and causes most of the clinically significant events. In this study, we evaluated the efficacy of nanoparticles (NPs) to differentiate between two plaque phenotypes based on accumulation kinetics in a mouse model of atherosclerosis. This model uses a perivascular cuff to induce two regions of disturbed wall shear stress (WSS) on the inner lining of the instrumented artery, low (upstream) and multidirectional (downstream), which, …

Pd Doped Sno2 Resistive Film As A Non-Enzymatic Glucose Sensor, Salim F. Bamsaoud, Sandhya Rani, R. N. Karekar Prof., S. W. Gosavi

Hadhramout University Journal of Natural & Applied Sciences

A new sugar sensor based on metal oxide is presented here. The variation on the sensor resistance is studied against different glucose and fructose concentrations (1 - 360 mg/dl). The study is done for three different resistive films (i) pristine palladium oxide (PdOx); (ii) tin oxide (SnO2) and (iii) palladium doped tin oxide (Pd-SnO2). The chemical reactions of glucose and fructose with surface species were studied. Pd-SnO2 films show an excellent and reliable response to glucose and fructose solution in comparison with the bare films (PdOx and SnO2). Sensor performance was checked for the blood of normal (120 mg/d) and …

Microfabricated Platforms To Investigate Cell Mechanical Properties, Amir M. Esfahani, Grayson Minnick, Jordan Rosenbohm, Haiwei Zhai, Xiaowei Jin, Bahareh Tajvidi Safa, Justin Brooks, Ruiguo Yang

Mechanical & Materials Engineering Faculty Publications

Mechanical stimulation has been imposed on living cells using several approaches. Most early investigations were conducted on groups of cells, utilizing techniques such as substrate deformation and flow-induced shear. To investigate the properties of cells individually, many conventional techniques were utilized, such as AFM, optical traps/optical tweezers, magnetic beads, and micropipette aspiration. In specific mechanical interrogations, microelectro- mechanical systems (MEMS) have been designed to probe single cells in different interrogation modes. To exert loads on the cells, these devices often comprise piezo-electric driven actuators that attach directly to the cell or move a structure on which cells are attached. Uniaxial …

Incorporation Of Zinc In Pre-Alloyed Cuin[Zn]S2/Zns Quantum Dots, Jean Carlos Morales Orocu

Graduate Theses and Dissertations

Since the early 2000s heavy-metal-free quantum dots (QDs) such as CuInS2/ZnS have attempted to replace CdSe, their heavy-metal-containing counterparts. CuInS2/ZnS is synthesized in a two-step process that involves the fabrication of CuInS2 (CIS) nanocrystals (NCs) followed by the addition of zinc precursors. Instead of the usual core/shell architecture often exhibited by binary QDs, coating CIS QDs results in alloyed and/or partially alloyed cation-exchange (CATEX) QDs. The effect that zinc has on the properties of CIS NCs was studied by incorporating zinc during the first step of the synthesis. Different In:Cu:Zn ratios were employed in this study, maintaining a constant 4:1 …

Silver Microparticle And Submicron Wire - Polylactic Acid Composites For Additive Manufacturing, Jenna W. Robichaux

University of New Orleans Theses and Dissertations

This thesis explores the incorporation of silver microparticle and submicron wire additives into thermoplastic filament feedstock for fused filament fabrication (FFF) to create multifunctional three-dimensional (3D) printable composites. The impact of silver microparticle and submicron wire additives on mechanical behavior along with antibacterial effect of the silver microparticle and submicron wire additives on printed objects were assessed.

Composite FFF filaments were fabricated by solution processing, granulation, and extrusion. Differential Scanning Calorimetry (DSC) was conducted to measure the glass transition and melting point temperatures of the composite filaments for 3D printing. The effect of the additive addition on the thermal properties …

Recombinant Production And Purification Of Green Fluorescent Protein (Gfp)-Fused Metal Binding Protein For Palladium Nanoparticle Synthesis, Shadrach Ibinola

Graduate Theses and Dissertations

In lieu of chemical and physical methods, biologically guided synthesis is increasingly used as a cost-effective medium for the fabrication of nanoparticles (NP). Recently, a palladium metal binding sequence Pd4 (TSNAVHPTLRHL) has been demonstrated to be instrumental in the production of palladium (Pd) nanoparticles. Although, by eliminating the additional cost of purification of the protein, the crude lysate of E. coli containing Pd specific protein has been proven to be a viable cost-effective means for the synthesis of Pd NP, studies have not be done to ascertain the comparative catalytic activity of nanoparticles synthesized from both clarified lysate and pure …

Multifunctional Programmable Self-Assembled Nanoparticles In Nanomedicine, Yoshie Sakamaki

Graduate Theses and Dissertations

Developing methodologies to control the architecture of nanoparticles (NPs) at the atomic level prevents their inhomogeneity and leads to a variety of expected functions. Rationally designed nanoparticles can either be programmed or crystallized structures into pre-determined structures achieving tunable particle pore size and physiochemistry. In this dissertation, two broad classes of multifunctional nanoparticles are developed, metal-organic frameworks and DNA-NP aggregates.

Metal-organic frameworks are a novel class of highly porous crystalline materials built from organic linkers and metal cluster-based secondary building units. However, applications in bioremediation have not been developed very well especially in applications regarding drug delivery systems (DDS). The …

Synthesis Of Polyethylene Glycol-Based Hydrogels And Silver/Gold Nanostructures For Biomedical Applications, Isabelle Ishimwe Niyonshuti

Graduate Theses and Dissertations

This work focuses on the synthesis of biocompatible polyethylene glycol (PEG)-based hydrogels, silver nanoparticles (AgNPs), and silver-gold nanocages (Ag-AuNCs) for biomedical applications. The dissertation includes two parts with Part I on the work of PEG-based hydrogel for wound healing applications and Part II on the work of Ag/Au nanostructures for antimicrobial applications. Part I studies PEG-based hydrogel for the delivery of fibroblast growth factors (FGFs) for wound healing applications, aiming to overcome the challenge of designing hydrogels capable of the sustained release of bioactive FGFs. This research develops new biocompatible anionic injectable hydrogel formulations based on Poly (Oligo Ethylene Glycol …

Dreams Of Molecular Beams: Indium Gallium Arsenide Tensile-Strained Quantum Dots And Advances Towards Dynamic Quantum Dots (Moleculare Radiorum Somnia: Indii Gallii Arsenicus Tensa Quanta Puncta Et Ad Dinamicae Quantae Puntae Progressus), Kevin Daniel Vallejo

Boise State University Theses and Dissertations

Through the operation of a molecular beam epitaxy (MBE) machine, I worked on developing the homoepitaxy of high quality InAs with a (111)A crystallographic orientation. By tuning substrate temperature, we obtained a transition from a 2D island growth mode to step- ow growth. Optimized MBE parameters (substrate temperature = 500 °C, growth rate = 0.12 ML/s and V/III ratio ⩾ 40) lead to growth of extremely smooth InAs(111)A films, free from hillocks and other 3D surface imperfections. We see a correlation between InAs surface smoothness and optical quality, as measured by photoluminescence spectroscopy. This work establishes InAs(111)A as a platform …

Quick - Release End Effector Tool Interface, Shane Farritor, Thomas Frederick

Mechanical & Materials Engineering Faculty Publications

The various embodiments herein relate to a coupling apparatus for a medical device having a coupler body, a cavity defined in the coupler body, a rotatable drive component disposed within the cavity and having at least two pin receiving openings, and an actuable locking ring disposed around the cavity.

Modeling And Simulation Of Janus-Like Nanoparticles Formation By Solid-Gas Exothermic Reactions, A. A. Markov, Karen S. Martirosyan

Physics and Astronomy Faculty Publications and Presentations

Theoretical model for the simulation of synthesis of Janus-like particles (JP) consisting two different phases using the Carbon Combustion Synthesis of Oxides (CCSO) is presented. The model includes the variation of sample initial porosity, carbon concentration and oxygen flow rate used to predict the formation of JP features. The two temperature (2T) combustion model of chemically active submicron-dispersed mixture of two phases including ferroelectric and ferromagnetic was implemented and assessed by using the experimentally estimated activation energy of 112±3.3 kJ/mol and combustion temperature. The experimental values allowed to account the thermal and concentration expansion effect along with the dispersion by …

The Primarily Undergraduate Nanomaterials Cooperative: A New Model For Supporting Collaborative Research At Small Institutions On A National Scale, Steven M. Huges, Mark P. Hendricks, Katherine M. Mullaugh, Mary E. Anderson, Anne K. Bently, Justin G. Clar, Clyde A. Daly Jr., Mark D. Ellison, Z. Vivian Feng, Natalia I. Gonzalex-Pech, Leslie S. Hamachi, Christine L. Heinecke, Joseph D. Keene, Adam M. Maley, Andrea M. Munro, Peter N. Njoki, Jacob H. Olshansky, Katherine E. Plass, Kathryn R. Riley, Matthew D. Sonntag, Sarah K. St. Angelo, Lucas B. Thompson, Emily J. Tollefson, Lauren E. Toote, Korin E. Wheeler

Chemistry Faculty Publications

The Primarily Undergraduate Nanomaterials Cooperative (PUNC) is an organization for research-active faculty studying nanomaterials at Primarily Undergraduate Institutions (PUIs), where undergraduate teaching and research go hand-in-hand. In this perspective, we outline the differences in maintaining an active research group at a PUI compared to an R1 institution. We also discuss the work of PUNC, which focuses on community building, instrument sharing, and facilitating new collaborations. Currently consisting of 37 members from across the United States, PUNC has created an online community consisting of its Web site (nanocooperative.org), a weekly online summer group meeting program for faculty and students, …

Enhanced Anticancer Response Of Curcumin- And Piperine-Loaded Lignin-G-P (Nipam-Co-Dmaema) Gold Nanogels Against U-251 Mg Glioblastoma Multiforme, Bilal Javed, Xinyi Zhao, Daxiang Cui, James Curtin, Furong Tian

Articles

Glioblastoma multiforme (GBM) is the most aggressive and commonly diagnosed brain cancer and is highly resistant to routine chemotherapeutic drugs. The present study involves the synthesis of Lignin-g-p (NIPAM-co-DMAEMA) gold nanogel, loaded with curcumin and piperine, to treat GBM. The ongoing study has the application potential to (1) overcome the limitations of drugs biodistribution, (2) enhance the toxicity of anticancer drugs against GBM, and (3) identify the drugs uptake pathway. Atom transfer radical polymerization was used to synthesize the Lignin-g-PNIPAM network, crosslinked with the gold nanoparticles (GNPs) to self-assemble into nanogels. The size distribution and morphological analysis confirmed that the …

Tailoring Plasmon Excitations In Alpha − T 3 Armchair Nanoribbons, Andrii Iurov, Liubov Zhemchuzhna, Godfrey Gumbs, Danhong Huang, Paula Fekete, Farhana Anwar, Dipendra Dahal, Nicholas Weekes

Publications and Research

We have calculated and investigated the electronic states, dynamical polarization function and the plasmon excitations for α − T ₃ nanoribbons with armchair-edge termination. The obtained plasmon dispersions are found to depend significantly on the number of atomic rows across the ribbon and the energy gap which is also determined by the nanoribbon geometry. The bandgap appears to have the strongest effect on both the plasmon dispersions and their Landau damping. We have determined the conditions when relative hopping parameter α of an α − T ₃ lattice has a strong effect on the plasmons which makes our material distinguished …