Nanoscience and Nanotechnology Commons^™

A Pilot Study On The Nanoscale Properties Of Bone Tissue Near Lacunae In Fracturing Women, Wen Qian, Roman Schmidt, Joseph A. Turner, Sue P. Bare, Joan M. Lappe, Robert R. Recker, Mohammed P. Akhter

Mechanical & Materials Engineering Faculty Publications

The goal of this study is to investigate the causes of osteoporosis-related skeletal fragility in postmenopausal women. We hypothesize that bone fragility in these individuals is largely due to mineral, and/or intrinsic material properties in the osteocyte lacunar/peri-lacunar regions of bone tissue. Innovative measurements with nanoscale resolution, including scanning electron microscope (SEM), an atomic force microscope that is integrated with infrared spectroscopy (AFM-IR), and nanoindentation, were used to characterize osteocyte lacunar and peri-lacunar properties in bone biopsies from fracturing (Cases) and matched (Age, BMD), non-fracturing (Controls) postmenopausal healthy women. In the peri-lacunar space, the nanoindentation results show that the modulus …

Characterization Of Electrophoretic Deposited Zinc Oxide Nanopartices For The Fabrication Of Next-Generation Nanoscale Electronic Applications, Fawwaz Abduh A. Hazzazi

LSU Doctoral Dissertations

Several reports state that it is crucial to analyze nanoscale semiconductor materials and devices with potential benefits to meet the need for next-generation nanoelectronics, bio, and nanosensors. The progress in the electronics field is as significant now, with modern technology constantly evolving and a greater focus on more efficient robust optoelectronic applications. This dissertation focuses on the study and examination of the practicality of Electrophoretic Deposition (EPD) of zinc oxide (ZnO) nanoparticles (NPs) for use in semiconductor applications.

The feasibility of several synthesized electrolytes, with and without surfactants and APTES surface functionalization, is discussed. The primary objective of this study …

Microfluidic Device For Localized Electroporation, Justin Brooks, Arian Jaberi, Ruiguo Yang

Mechanical & Materials Engineering Faculty Publications

Electroporation is a common method of transfection due to its relatively low risk and high transfection efficiency. The most common method of electroporation is bulk electroporation which is easily performed on large quantities of cells yet results in variable levels of viability and transfection efficiency across the population. Localized electroporation is an alternative that can be administered on a similar scale but results in much more consistent with higher quality transfection and higher cell viability. This paper discusses the creation and use of a simple and cost-effective device using porous membrane for performing localized electroporation.

Phase Space Analysis Of Nonlinear Wave Propagation In A Bistable Mechanical Metamaterial With A Defect, Mohammed A. Mohammed, Piyush Grover

Mechanical & Materials Engineering Faculty Publications

We study the dynamics of solitary waves traveling in a one-dimensional chain of bistable elements in the presence of a local inhomogeneity (`defect'). Numerical simulations reveal that depending upon its initial speed, an incoming solitary wave can get transmitted, captured or reflected upon interaction with the defect. The dynamics are dominated by energy exchange between the wave and a breather mode localized at the defect. We derive a reduced-order two degree of freedom Hamiltonian model for wave-breather interaction, and analyze it using dynamical systems techniques. Lobe dynamics analysis reveals the fine structure of phase space that leads to the complicated …

Two-Photon Nanomachining Of A Micromechanically Enhanced Optical Cavity Sensor On An Optical Fiber Tip, Jeremiah C. Williams, Hengky Chandrahalim, Joseph S. Suelzer, Nicholas G. Usechak

Faculty Publications

Herein, a two-photon nanostructuring process that is employed to monolithically integrate dynamic three-dimensional (3D) micromechanical features into Fabry–Pérot cavity (FPC) sensors on an optical fiber tip is demonstrated. These features represent a breakthrough in the integration and fabrication capabilities of micro optomechanical devices and systems. The demonstrated dynamic optical surface enables directional thin-film deposition onto obscured areas. The rotation of the dynamically movable mirror to deposit a thin reflective coating onto the inner surfaces of a FPC with curved geometry is leveraged. The reflective coating in conjunction with the dynamically rotatable mirror greatly improves the quality factor of the FPC …

Passive Radiative Cooling By Spectrally Selective Nanoparticles In Thick Film Nanocomposites, David Allen Young

USF Tampa Graduate Theses and Dissertations

Passive cooling of buildings is a benefit to society since no energy input is required for space cooling which reduces electricity consumption, fossil fuel burning, and greenhouse gas emissions. When a passive cooling technology radiates heat from the earth through the atmospheric windows to space higher levels of cooling power are possible -- this phenomenon is classified as passive “radiative” cooling. Spectrally selective surface coatings provide radiative cooling to lower surface temperatures by reflecting most solar radiation, while emitting infrared radiation at wavelengths between 8-13 μm through the primary atmospheric window to the cold of space. Multiple applications of radiative …

Modular Cable - Driven Surgical Robots, Carl A. Nelson, Nicholas Nelson

Mechanical & Materials Engineering Faculty Publications

A surgical robot can be configured for minimally invasive surgery ( MIS ) and other types of surgery with modular link geometry and disposable components. In some examples, the surgical robot includes a cable driver comprising at least one drive motor configured for tensioning a cable. The surgical robot includes an articulated surgical tool coupled to the drive motor by the cable. The articulated surgical tool comprises at least first and second articulated links and a joint coupling the first and second articulated links. The cable passes through the joint, and the joint comprises an elastic antagonist biased in opposition …

The Dark Annulus Of A Drop In A Hele-Shaw Cell Is Caused By The Refraction Of Light Through Its Meniscus, Sangjin Ryu, Haipeng Zhang, Carson Emeigh

Mechanical & Materials Engineering Faculty Publications

Knowing the meniscus shape of confined drops is important for understanding how they make first contact and then coalesce. When imaged from the top view by brightfield microscopy, a liquid drop (e.g., corn syrup) confined in a Hele-Shaw cell, surrounded by immiscible liquid (e.g., mineral oil), had a dark annulus, and the width of the annulus decreased with increasing concentration of corn syrup. Since the difference in the annulus width was presumed to be related to the meniscus shape of the drops, three-dimensional images of the drops with different concentrations were obtained using confocal fluorescence microscopy, and their cross-sectional meniscus …

Biomimetic Strategies To Control Therapeutic Release From Novel Dna Nanoparticles, Robert J. Mosley

Theses and Dissertations

The inherent chemical, mechanical, and structural properties of nucleic acids make them ideal candidates for the formulation of tunable, personalized drug nanocarriers. However, none so far have exploited these properties for the controlled release of therapeutic drugs. In this dissertation, a biomimetic approach to controlling drug release is exhibited by specifically manipulating the architecture of novel, DNA nanoparticles to take advantage of drug binding mechanisms of action. Rationally designed DNA strands were immobilized on gold surfaces via a terminal thiol modification. Immobilized monomers can be manipulated to form distinct monolayer architectures including flat, folded, coiled, or stretched structures. Increasing the …

Gross Positioning Device And Related Systems And Methods, Mark A. Reichenbach, Shane M. Farritor

Mechanical & Materials Engineering Faculty Publications

Disclosed herein are gross positioning systems for use with robotic surgical devices to provide gross positioning of the robotic surgical devices. The gross positioning systems have a base, a first arm link operably coupled to the base, a second arm link operably coupled to the first arm link, a third arm link operably coupled to the second arm link, and a slidable coupling component slidably coupled to the third arm link.

Carbon Nanotube-Based Microscale Capacitive Flow Sensors, Nathaniel Holmes

Electronic Thesis and Dissertation Repository

Micro-scale flow sensors present several advantages over traditional flow sensing
methods, including minimal flow disruption, high spatial resolution, and low unit
cost. Many existing micro-scale thermal and piezo flow sensors struggle with temperature drift and require complicated fabrication processes. This thesis details
the development of a 60 μm by 60 μm by 50 μm drag-based capacitive flow sensor
constructed from vertically aligned carbon nanotube forests. The construction
of a thermal chemical vapour deposition system for sensor synthesis is also de-
tailed. Manual manipulation of the sensor with an atomic force microscope probe
was found to produce a full scale signal …

A Python Implementation Of The Quasi-Harmonic Approximation: Ab-Initio Study Of The Thermoelastic Properties Of Magnesium Oxide And Calcium Oxide, Adewumi Bakare

Dissertations, Theses, and Capstone Projects

When heated up, materials change volume, typically they expand, and they also change their elastic properties, typically by softening. Computational methods to calculate materials properties at finite temperature are needed to compensate for the lack of experimental data, as well as to predict materials properties at conditions difficult to be reached in experimental labs. In this research project, I designed a set of Python codes implementing a quasi-harmonic approximation (QHA) method to calculate thermodynamic functions at constant volume, equation of state, and the isothermal Bulk modulus of cubic materials. To validate the new computational tools, this implementation of QHA has …

Uv Space Imager Enclosure Coating, David Silva Cortez, Victor Alexander Rempel Dekhtyar, Maria L. Muñoz

Mechanical Engineering

The goal of this project is to reduce the amount of stray light entering an ultraviolet (UV) imager through absorption. This report outlines the use of ZnO nanoparticles mixed in an epoxy matrix for use in a CubeSat enclosure. Through testing, our team verified that the ZnO and epoxy coating experienced a peak absorption between 360-370 nm. The epoxy mixture with the .75% by weight ZnO nanoparticles absorbed up to 99.9 % of UV light at its peak. The effect on material properties, such as Young’s modulus and ultimate tensile strength, was also tested. Tensile tests demonstrated that adding ZnO …

Monolithic Integration Of Hybrid Perovskite Single Crystals With Silicon For Highly Sensitive X - Ray Detectors, Jinsong Huang, Wei Wei

Mechanical & Materials Engineering Faculty Publications

Perovskite single crystal X - ray radiation detector devices including an X - ray wavelength - responsive active layer including an organolead trihalide perovskite single crystal, a substrate layer comprising an oxide, and a binding layer disposed between the active layer and the substrate layer. The binding layer including a binding molecule having a first functional group that bonds to the organolead trihalide perovskite single crystal and a second functional bonds with the oxide. Inclusion of the binding layer advantageously reduces device noise while retaining signal intensity.

Passivation Of Defects In Perovskite Materials For Improved Solar Cell Efficiency And Stability, Jinsong Huang, Xiaopeng Zheng

Mechanical & Materials Engineering Faculty Publications

Semiconductor devices , and methods of forming the same , include a cathode layer , an anode layer , and an active layer disposed between the cathode layer and the anode layer , wherein the active layer includes a perovskite layer . A passivation layer is disposed directly on a surface of the active layer between the cathode layer and the active layer , the passivation layer including a layer of material that passivates both cationic and anionic defects in the surface of the active layer .

Application Of Bismuth Oxychloride As A Colorimetric Uv Sensor Material, Kyle James Troche

Nanoscience and Microsystems ETDs

Sunlight contains about 9% UV radiation with roughly one-third of it penetrating the atmosphere and reaching the Earth’s surface. UV radiation from the sun is classified into three different types: UVA (315- 499 nm), UVB (280- 314nm), and UVC (100- 279 nm). Prolonged exposure to artificial UV radiation or direct sunlight can still induce many adverse effects such as sunburn, weakening of the immune system, and skin cancer. A wide variety of photoresistor, photodiode and colorimetric UV sensors are currently being researched to help monitor UV radiation. Our research is focused on developing a colorimetric UV sensor that is inherently …

Thermal Management Using Liquid-Vapor Phase Change In Nanochannels, Sajag Poudel

Dissertations - ALL

Superior wettability of porous medium marks their potential to be used in the field of thermal management employing phase-change heat transfer. Comprehending the phenomena of wicking and liquid-vapor phase-change in micro/nano structured surfaces are key aspects towards advancing heat transfer solutions. In this work, fundamental understanding of droplet wicking, thin-film evaporation, and their subsequent application of heat-flux removal for cooling technology is first reported. The latter part of the dissertation is related to the disjoining pressure driven flow of nanoscale liquid film and liquid-vapor phase change in nano confinement. First, experimental and numerical investigation of droplet wicking in ∼728 nm …

Surface Acoustic Wave Characterization And Interdigitated Transducer Optimization For Studying Stress-Enhanced Phenomena, Brian D. Rummel

Nanoscience and Microsystems ETDs

Surface acoustic wave devices have not yet achieved their full potential as the effects of standing acoustic fields on stress-sensitive phenomena in semiconductor systems have been largely unexplored. From this perspective, it is necessary to develop novel methods to characterize surface acoustic wave devices quantitatively and prepare an experimental platform to probe stress-enhanced processes. In this dissertation, interdigitated transducer devices are fabricated on gallium arsenide to evaluate their potential impact on strain-enhanced phenomena. A novel Raman characterization technique characterizes the surface stress induced by a standing acoustic field, revealing stress values on the order of 10⁸ Pa. FEM software …

Resistive Pulse Sensing Of Protein Unfolding And Transport In Solid-State Nanopores, Jugal Saharia

Mechanical Engineering Research Theses and Dissertations

Solid-state nanopore sensors have attracted considerable attraction as a tool for solution-based single-molecule studies and have been successfully utilized for characterization of biomolecules such as nucleic acids, proteins, glycans, viruses, etc. Among these, characterization of proteins has been more challenging due to their charge heterogeneity and the complex energy landscape associated with different protein conformations. Presented in this thesis is the fabrication of solid-state nanopores and their application for characterizing proteins and understanding their transport through nanopores. Fabrication of nanometer-sized pores in Si_xN_y membranes was achieved using the conventional controlled dielectric breakdown method as well as a …

Photocatalytic Degradation Of Organic Contaminants By Titania Particles Produced By Flame Spray Pyrolysis, Noah Babik

Theses and Dissertations

Advanced oxidation of organic pollutants with TiO2 photocatalysts is limited due to the wide bandgap of TiO2, 3.2 eV, which requires ultraviolet (UV) radiation. When nanosized TiO2 is modified by carbon doping, charge recombination is inhibited and the bandgap is narrowed, allowing for efficient photodegradation under visible light. Here, we propose a flame spray pyrolysis (FSP) technique to create TiO2. The facile process of FSP has been successful in preparing highly crystalline TiO2 nanoparticles. Using the same procedure to deposit TiO2 onto biochar, the photocatalyst was doped by the carbonaceous material. The morphology, crystalline and electronic structure of the FSP …