Assessing Adoption Barriers Of Sustainable Packaging In Egypt, 2024 American University in Cairo
Assessing Adoption Barriers Of Sustainable Packaging In Egypt, Carol Ramses Morgan
Theses and Dissertations
Sustainable packaging has become an essential part of business decisions and corporate directions. With the rise of environmental damages due to improper waste management and unsustainable practices, businesses have a major responsibility to analyze their products’ life cycles and redesign them with sustainability in mind. Applying sustainable packaging could save companies large amounts of resources, therefore cutting costs, while also achieving the legal and social duty as a corporation towards society and the environment. Many developing countries, with specific focus on Egypt, have recently focused on legislative and corporate decisions in order to encourage more sustainable practices. Egypt’s new Waste …
Rational Design Of Peptide-Based Materials Informed By Multiscale Molecular Dynamics Simulations, 2024 The Graduate Center, City University of New York
Rational Design Of Peptide-Based Materials Informed By Multiscale Molecular Dynamics Simulations, Dhwanit Rahul Dave
Dissertations, Theses, and Capstone Projects
The challenge of establishing a sustainable and circular economy for materials in medicine and technology necessitates bioinspired design. Nature's intricate machinery, forged through evolution, relies on a finite set of biomolecular building blocks with through-bond and through-space interactions. Repurposing these molecular building blocks requires a seamless integration of computational modeling, design, and experimental validation. The tools and concepts developed in this thesis pioneer new directions in peptide-materials design, grounded in fundamental principles of physical chemistry. We present a synergistic approach that integrates experimental designs and computational methods, specifically molecular dynamics simulations, to gain in-depth molecular insights crucial for advancing the …
Limits Of Economy And Fidelity For Programmable Assembly Of Size-Controlled Triply-Periodic Polyhedra, 2024 Max Planck Institute of Molecular Cell Biology and Genetics
Limits Of Economy And Fidelity For Programmable Assembly Of Size-Controlled Triply-Periodic Polyhedra, Carlos M. Duque, Douglas M. Hal, Botond Tyukodi, Michael F. Hagan, Christian D. Santangelo, Gregory M. Grason
Data and Datasets
We propose and investigate an extension of the Caspar-Klug symmetry principles for viral capsid assembly to the programmable assembly of size-controlled triply-periodic polyhedra, discrete variants of the Primitive, Diamond, and Gyroid cubic minimal surfaces. Inspired by a recent class of programmable DNA origami colloids, we demonstrate that the economy of design in these crystalline assemblies -- in terms of the growth of the number of distinct particle species required with the increased size-scale (e.g. periodicity) -- is comparable to viral shells. We further test the role of geometric specificity in these assemblies via dynamical assembly simulations, which show that conditions …
Modeling Of Asphalt Concrete For Cross-Anisotropic Visco-Elasticity And Heterogeneity, 2023 University of New Mexico - Main Campus
Modeling Of Asphalt Concrete For Cross-Anisotropic Visco-Elasticity And Heterogeneity, Zafrul Hakim Khan
Civil Engineering ETDs
Asphalt Concrete (AC) is a cross-anisotropic viscoelastic material. This study has developed a methodology to backcalculate the cross-anisotropic properties of the AC layer from the Falling Weight Deflectometer (FWD) sensor and pavement response data from embedded sensors inside a pavement section. This study has also developed a two-way coupled Multiscale Finite Element Model (MsFEM) with Phase Field Fracture (PFF) to study the microstructural heterogeneity and damage of the AC layer based on the actual field loadings. A Finite Difference Time Domain (FDTD) and Machine learning-based backcalculation algorithm were developed to determine the layer thickness and dielectric constant from air-coupled Ground …
Design, Fabrication And Characterization Of Zero Power Sensor/Harvester For Smart Grid Applications, 2023 University of New Mexico
Design, Fabrication And Characterization Of Zero Power Sensor/Harvester For Smart Grid Applications, Zeynel Guler
Mechanical Engineering ETDs
This study presents a flexible sensor/harvester device to be used in both electromagnetic sensing and energy harvesting applications for smart grids. When a current passes through a wire, the sensor detects the magnetic field created by that current. The sensor magnet interacts with the wire magnetic field resulting in a transfer of energy through the piezoelectric cantilever. Piezoelectric, conductive, magnetic, and magnetostrictive composite thin films were prepared to fabricate this device.
Initially, the magnet of the cantilever was optimized considering its shape, thickness, length, taper angle etc. via both simulations and experiments. Peak to peak voltage versus cantilever position graph …
Thermally Rearranging Polyimide Networks For High-Temperature Applications, 2023 The University of Southern Mississippi
Thermally Rearranging Polyimide Networks For High-Temperature Applications, William Guzman
Dissertations
High-performance polymers can retain functional properties when exposed to long-term or short-term durations of harsh conditions, such as mechanical action, at elevated temperatures (>177 °C). A mixture of intramolecular and intermolecular forces of and between polymer chains provide excellent property retention at elevated temperatures. Specifically, the highly aromatic nature of high-performance polymer backbones provides outstanding thermal stability, which is typically attributed to π-π stacking. However, the interrelationship between thermal stability and high aromaticity creates a challenging structure-processing relationship paradigm, which causes poor polymer processability in most high-performance polymers. Herein, it was demonstrated that rationally designing a crosslinking phenylethynyl imide …
A Comprehensive Review On Metal Oxide-Nanocellulose Composites In Sustainable Active And Intelligent Food Packaging, 2023 Technological University Dublin
A Comprehensive Review On Metal Oxide-Nanocellulose Composites In Sustainable Active And Intelligent Food Packaging, Kalpani Y. Perera, Amit Jaiswal, Swarma Jaiswal, Dileswar Pradhan
Articles
The aim of this article is to provide an overview of the potential advantages and drawbacks of nanocellulose and metal oxide-based composites in food packaging. These materials offer improved mechanical and barrier properties, as well as antioxidant and antimicrobial benefits that extend the shelf life of food products. Nanocomposite structures protect food from various physiological factors and immobilize enzymes, while metal oxide nanoparticles provide antibacterial effects against Gram-positive and Gram-negative bacteria. However, there are concerns regarding the safety of nanoparticles and their potential migration into packaged food during processing and storage. This article explores these issues and highlights the need …
Characterization Of Interlayer Laser Shock Peening During Fused Filament Fabrication Of Polylactic Acid (Pla), 2023 University of Nebraska-Lincoln
Characterization Of Interlayer Laser Shock Peening During Fused Filament Fabrication Of Polylactic Acid (Pla), Fabien Denise
Department of Engineering Mechanics: Dissertations, Theses, and Student Research
The field of additive manufacturing (AM) has gained a significant amount of popularity due to the increasing need for more sustainable manufacturing techniques and the adaptive development of complex product geometries. The problem is that AM parts routinely exhibit flaws or weaknesses that affect functionality or performance. Over the years, surface treatments have been developed to compensate certain flaws or weaknesses in manufactured products. Combining surface treatments with the modularity of additive manufacturing could lead to more adaptable and creative improvements of product functions in the future. The current work evaluates the feasibility of pursuing a new research axis in …
Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, 2023 Florida Institute of Technology
Analyzing The Effects Of Ultrafast Laser Processing On Mechanical Properties Of 3d-Printed Pla Parts, Darshan Pramodbhai Yadav
Theses and Dissertations
Recent advances in additive manufacturing technologies have already led to wide-scale adoption of 3D-printed parts in various industries. The expansion in choice of materials that can be processed, particularly using Fused Deposition Modeling (FDM), and the steady advancements in dimensional accuracy control have extended the range of applications far beyond rapid prototyping. However, additive manufacturing still has considerable limitations compared to traditional and subtractive manufacturing processes. This work addresses limitations associated with the as-deposited surface roughness of 3D-printed parts. The effects of roughness-induced stress concentrations were studied on ultimate tensile strength and fatigue life. The samples were manufactured using a …
Modular Composite Sandwich Structures For Thermal And Structural Retrofitting Of Existing Buildings, 2023 University of Tennessee, Knoxville
Modular Composite Sandwich Structures For Thermal And Structural Retrofitting Of Existing Buildings, Marc Al Ghazal
Masters Theses
Around 40% of global energy consumption and 30% of worldwide carbon dioxide (CO2) emissions are attributed to buildings. Most of this consumption is dedicated to ensuring thermal comfort. The goal of this research was to develop and field validate retrofit solutions to improve the energy efficiency of buildings. Exterior cladding panels were designed and tested to ensure adequate thermal and structural performance. Sandwich panels (glass fibers reinforced polymer (GFRP) skins and polymeric foam cores) were fabricated using the vacuum assisted resin transfer molding (VARTM) process. Extruded polystyrene (XPS) and polyurethane (PU) foams were compared as core materials through a series …
Fabrication Of Alumina Membranes From Uv Resin– Alumina Particle Slurries, 2023 California Polytechnic State University, San Luis Obispo
Fabrication Of Alumina Membranes From Uv Resin– Alumina Particle Slurries, Dominique Henry Porcincula
Master's Theses
Ceramics membranes are made in a wide variety of different techniques using a wide variety of different materials. However, many of the common techniques utilize a slurry of ceramic particles, additives, and either organic solvent or water that is shaped into a membrane, left to dry, and then sintered together. Drying is a time consuming process, often requiring several hours for the liquid medium to evaporate. Defect formation caused by development of partial pressures across the drying membrane, including cracks and warpage, also typically occurs during the drying process. To address this, slurries of ceramic particles made with a low …
Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, 2023 Clemson University
Cfrp Delamination Density Propagation Analysis By Magnetostriction Theory, Brandon Eugene Williams
All Dissertations
While Carbon Fiber Reinforced Polymers (CFRPs) have exceptional mechanical properties concerning their overall weight, their failure profile in demanding high-stress environments raises reliability concerns in structural applications. Two crucial limiting factors in CFRP reliability are low-strain material degradation and low fracture toughness. Due to CFRP’s low strain degradation characteristics, a wide variety of interlaminar damage can be sustained without any appreciable change to the physical structure itself. This damage suffered by the energy transfer from high- stress levels appears in the form of microporosity, crazes, microcracks, and delamination in the matrix material before any severe laminate damage is observed. This …
Interfacial Thermomechanical Behavior Of Hybrid Carbon Fibers, 2023 Embry-Riddle Aeronautical University
Interfacial Thermomechanical Behavior Of Hybrid Carbon Fibers, Sriraj Srihari
Doctoral Dissertations and Master's Theses
The carbon fiber/epoxy interface is of great importance in composite design due to its load transfer mechanisms from the weak epoxy to the stronger fiber. Improving the strength of the interface reduces the risk of failure at the interface and improves the load transfer to the fiber. In this study, two types of nano-species ZnO nanowires and nickel-based metal organic frameworks were grown on carbon fibers to improve the interfaces. The interfacial mechanics of the enhanced fibers are evaluated using nanoindentation studies. Composite samples with Aeropoxy matrix and vertically aligned fibers are fabricated for this purpose. A Bruker TI-980 TriboIndenter …
Synergistic Effect Of Nanoclay And Barium Sulfate Fillers On The Corrosion Resistance Of Polyester Powder Coatings, 2023 Western University
Synergistic Effect Of Nanoclay And Barium Sulfate Fillers On The Corrosion Resistance Of Polyester Powder Coatings, Jinbao Huang, Marshall Shuai Yang, Chengqian Xian, James Joseph Noel, Yolanda S. Hedberg, Jian Chen, Ubong Eduok, Ivan Barker, Jeffrey Daniel Henderson, Haiping Zhang, Liqin Wang, Hui Zhang, Jesse Zhu
Chemistry Publications
No abstract provided.
Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, 2023 New Jersey Institute of Technology
Investigating The Rheological Behavior Of A Simple Yield Stress Fluid Under Shear Flows, Francesco Accetta
Theses
Many soft materials display unique and complex rheological behavior characterized by a transition from a solid-like to a fluid-like state upon the application of a force that exceeds the threshold to flow, known as the yield stress. Yield stress fluids are found in a wide range of commonly encountered materials including microgels, emulsions, and foams, and have been widely studied by rheologists over the last several decades. Carbopol is a popular polymeric microgel system as it displays simple, non-thixotropic rheological behavior and is typically seen as an ideal yield stress fluid. Previous research has demonstrated the reproducible behavior of shear …
Investigating The Effect Of Bead Geometry On Fiber Orientation And Thermomechanical Properties For Large-Format Extrusion-Based Additive Manufacturing, 2023 University of Maine
Investigating The Effect Of Bead Geometry On Fiber Orientation And Thermomechanical Properties For Large-Format Extrusion-Based Additive Manufacturing, Joanna F. Keaton
Electronic Theses and Dissertations
In large-format extrusion-based additive manufacturing of polymer composites, the relationship between material properties and processing parameters requires further investigation. This thesis focuses on the relationship between fiber orientation and thermomechanical properties for short fiber-filled thermoplastic polymer systems manufactured by extrusion-based additive manufacturing. Fiber orientation is particularly important in determining the thermomechanical properties of the composite material as properties in the direction of deposition are expected to be higher for highly aligned fibers than randomly aligned fibers. Fiber orientation distribution, which is related to processing parameters and deposition conditions, can be efficiently represented by the orientation tensor. The orientation tensor can …
Mechanical Characterization Of Automated Fiber Placement And Additive Manufacturing Hybrid Composites, 2023 University of Maine
Mechanical Characterization Of Automated Fiber Placement And Additive Manufacturing Hybrid Composites, Lucan Haviland
Electronic Theses and Dissertations
This thesis presents the optimization of processing parameters based on the mechanical properties of Continuous Fiber-Reinforced Thermoplastic (CFRTP) Unidirectional (UD) consolidated tapes. The UD tapes were consolidated using an AFP head and a thermoforming press for comparison. The adhesive strength of hybrid parts consisting of CFRTP UD tape bonded to a 3D-printed substrate with the same matrix system were investigated. Large Area Additive Manufacturing (LAAM) was utilized for the 3D-printed parts. Different types of thermoplastic composite materials were explored, including Glass Fiber reinforced Polyethylene Terephthalate Glycol (GF/PETG), Carbon Fiber reinforced Polyethylene Terephthalate Glycol (CF/PETG), Carbon Fiber reinforced Polycarbonate (CF/PC), and …
Numerical Modeling And Simulation On Deformation And Failure Behaviors Of Polymeric Materials, 2023 The University of Western Ontario
Numerical Modeling And Simulation On Deformation And Failure Behaviors Of Polymeric Materials, Heng Feng
Electronic Thesis and Dissertation Repository
Featured by biocompatibility, high compliance and capacity in sustaining large deformation, dielectric elastomers (DEs) and hydrogels have gained extensive research popularity for their potential applications in the fields of soft robots, biomimetics, tissue engineering, drug delivery, and energy harvesting. The design of such soft and smart material-based devices and structures requires deep understanding and accurate simulation of their constitutive behaviors, which is challenged by their nonlinear material properties due to unique microstructures and multi-physics coupling. Meanwhile, in different application contexts, those structures are also susceptible to different failure modes, imposing further challenges in simulating and predicting their performance. To fulfill …
Evaluation Of Biomass As Bio-Additive In 3d Printing, 2023 University of Tennessee, Knoxville
Evaluation Of Biomass As Bio-Additive In 3d Printing, Shuyang Zhang
Doctoral Dissertations
The petrol-based polymer has been widely applied in current daily life. The end-of-life of polymeric products has drawn environmental concerns. One of the solutions to such issues is to use bio-renewable materials to replace or reduce the use of petrol-based materials. Lignocellulosic materials are one of the potential candidates. Along with the features of 3D printing and the unique properties of biomass, 3D-printed biomass-based materials could be promising in preparing sustainable alternatives.
In this dissertation, lignin and other biomass were applied to various 3D printing techniques for sustainable composites. Stereolithography (SLA) was first used, and the kraft softwood lignin was …
Glass Bubbles Grafted With Polymer Brushes For Liquid Hydrocarbon Fire Extinguishment, 2023 Clemson University
Glass Bubbles Grafted With Polymer Brushes For Liquid Hydrocarbon Fire Extinguishment, Randall Snipes
All Dissertations
The current most efficient solution to fighting liquid pool fires involves the use of firefighting foams containing fluorinated surfactants. The physiochemical properties of these foams are considerably different to all other currently available firefighting foams. Fluorinated surfactants lower the surface tension to a point where the foam solution draining from the foam structure forms a continuous aqueous film on the surface of a volatile hydrocarbon fuel, adding an additional barrier to fuel vapor diffusion to the burning fire. For this reason, these foams qualify as aqueous film forming foams (AFFFs). However, fluorinated compounds are extremely harmful for the environment due …