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Characterization Of Virgin, Re-Used, And Oxygen-Reduced Copper Powders Processed By The Plasma Spheroidization Process, M. Hossein Sehhat, David Perez-Palomino, Connor Wiedemeier, Tristan Cullom, Joseph William Newkirk 2023 Missouri University of Science and Technology

Characterization Of Virgin, Re-Used, And Oxygen-Reduced Copper Powders Processed By The Plasma Spheroidization Process, M. Hossein Sehhat, David Perez-Palomino, Connor Wiedemeier, Tristan Cullom, Joseph William Newkirk

Mathematics and Statistics Faculty Research & Creative Works

Fabrication of parts with high mechanical properties heavily depend on the quality of powder deployed in the fabrication process. Copper powder in three different powder types were spheroidized using radio-frequency inductively coupled plasma (ICP) spheroidization process (TekSphero-15 system). The characterized powders include virgin powder as purchased from the powder manufacturer, powder used in electron beam powder bed fusion (EB-PBF) process, and reconditioned powder, which was used powder that underwent an oxygen-reduction treatment. The goal of spheroidizing these powder types was to evaluate the change in powder morphology, the possibility of enhancing the powder properties back to their as-received conditions, and …


In Situ And Real-Time Mold Flux Analysis Using A High-Temperature Fiber-Optic Raman Sensor For Steel Manufacturing Applications, Bohong Zhang, Hanok Tekle, Ronald J. O'Malley, Todd Sander, Jeffrey D. Smith, Rex E. Gerald, Jie Huang 2023 Missouri University of Science and Technology

In Situ And Real-Time Mold Flux Analysis Using A High-Temperature Fiber-Optic Raman Sensor For Steel Manufacturing Applications, Bohong Zhang, Hanok Tekle, Ronald J. O'Malley, Todd Sander, Jeffrey D. Smith, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

Continuous Casting in Steel Production Uses Specially Developed Oxyfluoride Glasses (Mold Fluxes) to Lubricate a Mold and Control the Solidification of the Steel in the Mold. the Composition of the Flux Impacts Properties, Including Basicity, Viscosity, and Crystallization Rate, All of Which Affect the Stability of the Casting Process and the Quality of the Solidified Steel. However, Mold Fluxes Interact with Steel during the Casting Process, Resulting in Flux Chemistry Changes that Must Be Considered in the Flux Design. Currently, the Chemical Composition of Mold Flux Must Be Determined by Extracting Flux Samples from the Mold during Casting and Then …


Temperature Monitoring In The Refractory Lining Of A Continuous Casting Tundish Using Distributed Optical Fiber Sensors, Muhammad Roman, Hanok Tekle, Dinesh Reddy Alla, Farhan Mumtaz, Jeffrey D. Smith, Laura Bartlett, Ronald J. O'Malley, Rex E. Gerald, Jie Huang 2023 Missouri University of Science and Technology

Temperature Monitoring In The Refractory Lining Of A Continuous Casting Tundish Using Distributed Optical Fiber Sensors, Muhammad Roman, Hanok Tekle, Dinesh Reddy Alla, Farhan Mumtaz, Jeffrey D. Smith, Laura Bartlett, Ronald J. O'Malley, Rex E. Gerald, Jie Huang

Materials Science and Engineering Faculty Research & Creative Works

This Article Explores the Prospects of using Spatially Distributed Optical Fiber Temperature Sensors based on Rayleigh Optical Frequency Domain Reflectometry (OFDR) Technology in the Continuous Casting of Molten Steel. the Measurement Capability of the Optical Fiber Sensors in a Simulated Steelmaking Environment Was Demonstrated using a Mock Refractory-Lined Tundish, Which Was Fabricated In-House. Single-Mode Optical Fibers, Contained in Protective Stainless-Steel Tubing, Were Embedded in the Refractory Lining of the Mock Tundish. the Instrumented Tundish Was Preheated Up to a Temperature of 960 °C (Recorded at the Surface of the Working Lining) Before the Molten Steel Pour. a Low-Alloy Steel (AISI …


Effect Of Sc On Recrystallization Resistance Of Aa7050, Keaton Schmidt 2023 Michigan Technological University

Effect Of Sc On Recrystallization Resistance Of Aa7050, Keaton Schmidt

Dissertations, Master's Theses and Master's Reports

The extrusion process involves high temperatures and strains that can result in undesirable microstructures, especially along the surface. Extruded alloys tend to exhibit surface recrystallization during heat treating at regions of higher strains, which can lead to reduced fatigue strength and corrosion resistance. By adding Sc to AA7050, nano-sized dispersoids are formed with Sc cores and Zr shells that restrict recrystallization more than the base alloy that only utilizes Zr. Billets with varying Sc content and a control with only Zr were cast, and extrusions were made in order to compare surface microstructures at varying strains in the as-extruded and …


Drop Wetting And Sliding On Soft, Swollen Elastomers, Zhuoyun Cai 2023 University of Kentucky

Drop Wetting And Sliding On Soft, Swollen Elastomers, Zhuoyun Cai

Theses and Dissertations--Chemical and Materials Engineering

Soft, slippery surfaces have gained increasing attention due to their wide range of potential applications, for example in self-cleaning, anti-fouling, liquid collection, and more. One design approach in creating slippery surfaces is using a swollen elastomer, which is a polymer network swollen with a lubricant. This type of surface may be beneficial for longer-term use than standard lubricant-infused surfaces, and provides a versatile surface with tunable mechanical properties. Hence, understanding the physics of soft surface interactions is important for fundamental soft matter physics, biomaterials, adhesives, and coatings. This research experimentally investigates wetting on soft infused networks, with the aim of …


Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif 2023 University of Kentucky

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …


Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller 2023 University of Utah, College of Mines and Earth Sciences

Size Distribution, Elemental Composition And Morphology Of Nanoparticles Separated From Respirable Coal Mine Dust, Shoeleh Assemi, Lei Pan, Xuming Wang, Titilayo Akinseye, Jan D. Miller

Michigan Tech Publications

Nanoparticles, defined as particles with one dimension below 100 nm, contribute little to the total mass concentration in respirable coal mine dust (RCMD) toxicological studies, but they could have a considerable part in the adverse health effects by RCMD inhalation. It has been shown that inhaled nanoparticles can penetrate deep into the lung and could plausibly contribute to acute and chronic pulmonary diseases by triggering oxidative stress formation and inducing inflammation. RCMD nanoparticles from samples collected in an underground mine in the United States were analyzed by a particle separation technique, field-flow fractionation (FFF), for size, morphology, and elemental composition. …


Carrier Transport Engineering In Wide Bandgap Semiconductors For Photonic And Memory Device Applications, Ravi Teja Velpula 2022 New Jersey Institute of Technology

Carrier Transport Engineering In Wide Bandgap Semiconductors For Photonic And Memory Device Applications, Ravi Teja Velpula

Dissertations

Wide bandgap (WBG) semiconductors play a crucial role in the current solid-state lighting technology. The AlGaN compound semiconductor is widely used for ultraviolet (UV) light-emitting diodes (LEDs), however, the efficiency of these LEDs is largely in a single-digit percentage range due to several factors. Until recently, AlInN alloy has been relatively unexplored, though it holds potential for light-emitters operating in the visible and UV regions. In this dissertation, the first axial AlInN core-shell nanowire UV LEDs operating in the UV-A and UV-B regions with an internal quantum efficiency (IQE) of 52% are demonstrated. Moreover, the light extraction efficiency of this …


Damage Stability Study Of A 500 Dw Ro-Ro Ferry Vessel, Zulfaidah Ariany, Budhi Santoso, Sarwoko Sarwoko, Nauval Abdurrahman Prasetyo 2022 Departement of Industrial Technology, Vocational School, Universitas Diponegoro, Semarang 50275, Indonesia

Damage Stability Study Of A 500 Dw Ro-Ro Ferry Vessel, Zulfaidah Ariany, Budhi Santoso, Sarwoko Sarwoko, Nauval Abdurrahman Prasetyo

Makara Journal of Technology

The development of the crossing transportation industry is currently increasing in the island areas. The use of Ro-Ro type ferry boats is extremely efficient in moving people, goods, and vehicles. The current research focuses on the damage stability of the 500 DWT Ro-Ro ferry, which aims to meet the needs of the Ro-Ro ferry in the archipelago area. The previously existing initial design of a barge hull with a main size Lpp = 40.15 m, B = 12 m, H = 3.2 m, and T = 2.15 m was used to analyze the damage stability condition further. First, the drawings …


Elucidating The Synergic Effect In Nanoscale Mos2/Tio2 Heterointerface For Na-Ion Storage, Chunrong Ma, Dewen Hou, Jiali Jiang, Yanchen Fan, Xiang Li, Tianyi Li, Zifeng Ma, Haoxi Ben, Hui Xiong 2022 Qingdao University

Elucidating The Synergic Effect In Nanoscale Mos2/Tio2 Heterointerface For Na-Ion Storage, Chunrong Ma, Dewen Hou, Jiali Jiang, Yanchen Fan, Xiang Li, Tianyi Li, Zifeng Ma, Haoxi Ben, Hui Xiong

Materials Science and Engineering Faculty Publications and Presentations

Interface engineering in electrode materials is an attractive strategy for enhancing charge storage, enabling fast kinetics, and improving cycling stability for energy storage systems. Nevertheless, the performance improvement is usually ambiguously ascribed to the “synergetic effect”, the fundamental understanding toward the effect of the interface at molecular level in composite materials remains elusive. In this work, a well-defined nanoscale MoS2/TiO2 interface is rationally designed by immobilizing TiO2 nanocrystals on MoS2 nanosheets. The role of heterostructure interface between TiO2 and MoS2 by operando synchrotron X-ray diffraction (sXRD), solid-state nuclear magnetic resonance, and density functional …


Computational Symmetric Grain Boundary Energy Of Thorium Dioxide, Brendan J. Carroll 2022 Georgia Southern University

Computational Symmetric Grain Boundary Energy Of Thorium Dioxide, Brendan J. Carroll

Honors College Theses

With fossil fuels being depleted at a faster rate than ever, there has been an effort to convert fossil fuel energy to different forms of green energy. One of these forms is nuclear power, and while nuclear power itself is not new, new fuel sources for different types of reactors are being developed. This study aims to do computational experiments on Thorium Dioxide (a potential new nuclear fuel source) to look for the lowest grain boundary energy and what the effect of grain boundary conditions on the energy. Different orientations of the materials grain boundary were modeled and molecular dynamic …


Reduction Of Embodied Carbon In Buildings Through Use Of Low Carbon Strategies And Standardization And Enforcement Of Life Cycle Assessment, Bhargavi Sai Sudhakar 2022 University of San Francisco

Reduction Of Embodied Carbon In Buildings Through Use Of Low Carbon Strategies And Standardization And Enforcement Of Life Cycle Assessment, Bhargavi Sai Sudhakar

Master's Projects and Capstones

The building and construction industry is energy intensive and as of 2021, this industry is responsible for 37% of the total global greenhouse gas emissions. In previous studies of conventional buildings, the operational energy of a building contributed to 80% and the embodied energy contributed to 20% of the total life cycle energy. With increase in policies and standards that focus on reducing the operational energy, low energy and certified green buildings have emerged where the operational energy has considerably reduced. The relative and absolute share of embodied energy in these energy efficient buildings have increased due to excessive use …


Advances On Composite Cathodes For Lithium-Sulfur Batteries, Xi-Yao Li, Chang-Xin Zhao, Bo-Quan Li, Jia-Qi Huang, Qiang Zhang 2022 1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Advances On Composite Cathodes For Lithium-Sulfur Batteries, Xi-Yao Li, Chang-Xin Zhao, Bo-Quan Li, Jia-Qi Huang, Qiang Zhang

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries are deemed as high-promising next-generation energy storage technique due to their ultrahigh theoretical energy density, where the sulfur cathodes with high specific capacity guarantee the energy density advantage and directly determine the battery performances. After decades of exploration, the most promising sulfur cathodes are sulfur/carbon composite (S/C) cathodes and sulfurized polyacrylonitrile (SPAN) cathodes. In this manuscript, recent advances on S/C and SPAN cathodes in Li-S batteries are comprehensively reviewed. The electrochemical reaction circumstances on S/C and SPAN cathodes are firstly introduced and compared to reveal the working mechanisms of the two types of Li-S batteries. The S/C …


Enhanced Performance Of 3d Electroactive Polymer Transducers Via Hierarchical Structures, Frederick B. Holness 2022 The University of Western Ontario

Enhanced Performance Of 3d Electroactive Polymer Transducers Via Hierarchical Structures, Frederick B. Holness

Electronic Thesis and Dissertation Repository

Conjugated polymers (CPs) are a class of polymers that exhibit a change in size or shape in response to electrical stimuli. The unique combination of electrical and mechanical properties facilitates the fabrication of novel devices in a broad range of applications including: sensors, actuators, and lab-on-a-chip systems. The alternating single and double bonds along the polymer chain of CPs enables their electroactive properties but is also responsible for processability associated with CPs that has limited fabrication methods. Recently a photosensitive CP composite enabling additive manufacturing (AM) of 3D CP structures was developed. However, the introduction of a copolymer for mechanical …


Investigation Of The Effect Of Corundum Layer On The Heat Transfer Of Sic Slab, Sri Elsa Fatmi, Donanta Dhaneswara, Muhammad Anis, Ahmad Ashari 2022 University of Indonesia

Investigation Of The Effect Of Corundum Layer On The Heat Transfer Of Sic Slab, Sri Elsa Fatmi, Donanta Dhaneswara, Muhammad Anis, Ahmad Ashari

Journal of Materials Exploration and Findings (JMEF)

Aluminum is the most widely used metal in industry. Aluminum smelting is one of the important steps that needs to be carried out to produce products made of aluminum metal with good quality. In the process of smelting aluminum there are several problems that occur, one of which is the growth of corundum in Si C refractories which affects the quality of aluminum melt and the durability of Si C refractories. This research was conducted to see the heat transfer in Si C and the effect of the presence of Corundum on heat transfer. This research was carried out by …


Dynamic Rbi With Central Difference Method Approach In Calculation Of Uniform Corrosion Rate: A Casestudy On Gas Pipelines, M.Riefqi Dwi Alviansyah, Fernanda Hartoyo, Zahra Nadia Nurullia, Ari Kurniawan 2022 Departemen Metalurgi dan Material, Fakultas Teknik, Universitas Indonesia, Depok 16424, Indonesia

Dynamic Rbi With Central Difference Method Approach In Calculation Of Uniform Corrosion Rate: A Casestudy On Gas Pipelines, M.Riefqi Dwi Alviansyah, Fernanda Hartoyo, Zahra Nadia Nurullia, Ari Kurniawan

Journal of Materials Exploration and Findings (JMEF)

The oil and gas industry generally uses a piping system to drain fluids. Even though the pipes used have been well designed, the use of pipes as a means of fluid transportation still provides the possibility of failure that can occur at any time, one of which is due to uniform corrosion. The use of standard Risk Based Inspection (RBI) according to the API RBI 581 document has been widely used to anticipate potential failures to pipe components. The use of standard RBI can reduce the risk of failure significantly. Because the standard RBI considers the component risk value to …


The Comparison Of Pipe Thickness Selection Method Using Full Flange Rating And Non-Full Flange Rating Of Cryogenic Services In An Lng Plant Construction, Ari Agustar, Isdaryanto Iskandar, Wahyuaji Narottama Putra 2022 Atma Jaya Catholic University

The Comparison Of Pipe Thickness Selection Method Using Full Flange Rating And Non-Full Flange Rating Of Cryogenic Services In An Lng Plant Construction, Ari Agustar, Isdaryanto Iskandar, Wahyuaji Narottama Putra

Journal of Materials Exploration and Findings (JMEF)

Significant growth of gas demand as a source of power generation for domestic use and industries, mainly in the developed countries, has forced the effort to secure the gas supplies located thousands of miles away across the sea as an economical way of gas transportation instead of transporting by pipeline. LNG technology was created as the solution. Natural gas is refrigerated below its boiling point (-160oC to -162oC), known as cryogenic temperature or cryogenic service. Material of Construction (MOC) selection report showed that 304/304L and 316/316L Stainless Steel pipe could withstand and be suitable for this …


Structural Risk-Based Underwater Inspection (Rbui) As A Cost Reduction Of Field’S End Of Production Life, Ivan Fitrian Putra, Johny Wahyuadi Soedarsono, Mirza Mahendra, Yuki Haidir, Faisal Dwiyana Purnawarman, Iwan Sukirna, Widi Hernowo 2022 University of Indonesia

Structural Risk-Based Underwater Inspection (Rbui) As A Cost Reduction Of Field’S End Of Production Life, Ivan Fitrian Putra, Johny Wahyuadi Soedarsono, Mirza Mahendra, Yuki Haidir, Faisal Dwiyana Purnawarman, Iwan Sukirna, Widi Hernowo

Journal of Materials Exploration and Findings (JMEF)

Mubadala Petroleum operates offshore platforms in a southern Makassar Straits that needs to be periodically inspected. The cost for the inspection is massive due to the high cost of mobilization and demobilization of vessels including crew and equipment. In response of a new approach to reduce cost, a Risk-Based Underwater Inspection (RBUI) methodology is developed. This RBUI purpose is to reduce the inspection interval of the offshore platform, from every 2 years to a longer period[1]. There are existing RBUI methodologies, which are already developed and implemented in other companies[5]. Purpose of this paper is to …


Platinum-Iridium Alloys In Jewelry, Nathen C. Christa, Seth Walker, Dylan Hallman 2022 Nathen Cade Christa

Platinum-Iridium Alloys In Jewelry, Nathen C. Christa, Seth Walker, Dylan Hallman

ME 4133/6133 Mechanical Metallurgy

One of the most widely used metals on the periodic table is Platinum (Pt). The name is derived from the Spanish Platina, meaning “silver.” This malleable, ductile material is widely used in applications due to its unique chemical properties. A couple of these unique properties include a high melting point and good resistance to corrosion or chemical attack. Platinum materials have alloys that are indispensable in the chemical laboratory for electrodes. This allows for material applications in crucibles and dishes to withstand elevated temperatures. Platinum is used primarily in catalytic converters in vehicles converting emissions from the vehicle’s engine into …


High-Carbon Steel In Additive Manufacturing, Chidi N. Agusiegbe, Devin Morton, Emmanuel Moore 2022 Mississippi State University

High-Carbon Steel In Additive Manufacturing, Chidi N. Agusiegbe, Devin Morton, Emmanuel Moore

ME 4133/6133 Mechanical Metallurgy

High-carbon steel can be processed through numerous methods. The method that will be focused on primarily is processing high-carbon steel through means of additive manufacturing. Additive manufacturing is the industrial production name for 3D printing, a computer-controlled process that creates three-dimensional objects by depositing materials, usually in layers. AM methods like wire laser additive manufacturing (WLAM) and electron beam melting (EBM) are all common methods for fabricating high carbon steel. The perks associated with these methods are that they improve some drawbacks of the natural properties of high-carbon steel. This paper discusses the uses of these additive manufacturing methods along …


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