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The Effect Of Extended Saltwater Absorption And Uv Cure On The Compressive Properties Of Msla 3d-Printed Photopolymer Resin Samples With Printing Variations, Suzanne Dixon 2024 Florida Institute of Technology

The Effect Of Extended Saltwater Absorption And Uv Cure On The Compressive Properties Of Msla 3d-Printed Photopolymer Resin Samples With Printing Variations, Suzanne Dixon

Theses and Dissertations

Liquid Crystal Display (LCD) 3D printers, also known as Masked Stereolithography Apparatus (MSLA), is a type of vat polymerization printing technique that cures liquid resin into a solid object. This technique is relatively new. Consequently, there is a shortage of detailed research on the impact of long-term environmental exposure on the MSLA-printed materials. The research within this document informs engineers and scientists of resin compressive properties after extended exposure to saltwater and ultraviolet (UV) light. Saltwater absorption of the material was analyzed at atmospheric pressure, 30-psi, 60-psi, and 90-psi; the samples reached saturation in saltwater after 56 days. The variation …


Finding Short Range Order In High Entropy Alloys, Mariah Wakefield 2024 University of Tennessee, Knoxville

Finding Short Range Order In High Entropy Alloys, Mariah Wakefield

Masters Theses

In this project, chemical short-range order in four samples of the high entropy alloy FeMnAlC was investigated. X-ray diffraction measurements were performed at the Advanced Photon Source of Argonne National Laboratory in Chicago, IL. The data were then analyzed by curve fitting with mathematical Gaussian and Lorentzian functions. Conditional fitting was applied to the first and fourth samples to confirm the original curve fit. Conditional fitting was then used to adjust the determined indices of the Gaussian peaks in these samples so that they better reflected what was occurring in nature. From these indices, an increased unit cell was predicted …


Design And Optimization Of A Novel Monolithic Spring For High-Frequency Press-Pack Sic Fet Modules, Bogac Canbaz 2024 University of Nebraska-Lincoln

Design And Optimization Of A Novel Monolithic Spring For High-Frequency Press-Pack Sic Fet Modules, Bogac Canbaz

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Silicon Carbide (SiC) Field-Effect Transistor (FET) modules lead the way in power electronics, being superior in efficiency and robustness for high-frequency applications. The shift towards SiC from traditional silicon (Si)-based devices is driven by its superior thermal conductivity, higher electric field strength, and operational efficiency at elevated temperatures. These features are critical for the development of next-generation, grid-oriented power converters aimed at enhancing the reliability and sustainability of power systems. This research focuses on high-frequency press-pack (HFPP) SiC FET modules, addressing the primary challenge of miniaturizing SiC FET dies without compromising performance, through an innovative press-contact design essential for increased …


Release Of Small Molecules From Rubber: Effects Of Materials Properties, Mechanical Loading And Molecular Interactions, Yongcan Du 2024 Clemson University

Release Of Small Molecules From Rubber: Effects Of Materials Properties, Mechanical Loading And Molecular Interactions, Yongcan Du

All Dissertations

Release of small molecules from polymeric materials has wide applications in the delivery systems of active molecules such as drug, fragrance, and semiochemical. Rubber materials are good candidates for the excipients of those systems due to properties such as good flexibility, permeability, and biocompatibility. Factors like material properties, mechanical loading, and molecular interactions may affect the release of small molecules in those systems. Therefore, understanding how those factors affect the release is key to the formulation, design, and evaluation of those systems.

To study the effects of materials properties, vulcanized natural rubber sheets with different crosslink densities, loaded with small …


A Comprehensive Materials Approach To Thermal Management In Fiber Lasers, Bailey Meehan 2024 Clemson University

A Comprehensive Materials Approach To Thermal Management In Fiber Lasers, Bailey Meehan

All Dissertations

Optical fiber-based amplifiers and lasers enable a great many useful devices and conveniences. Unfortunately, however, they can generate considerable heat during operation that drives the need for complex cooling solutions, thus reducing many of the size, weight, and power (SWAP) benefits for which fiber lasers are known. Additionally, at elevated temperatures, thermally-driven phenomena, such as Transverse Mode Instability (TMI), can be induced that limit the power-scaling of fiber lasers. The focus of this Dissertation is to explore novel approaches to thermal management in fiber lasers through judicious materials science and engineering to obviate the aforementioned limitations. Fibers studied in this …


Engineering Multifunctional Silicon Nanostructures From Biorenewable Cellulose Nanocrystals, Nancy Chen 2024 Clemson University

Engineering Multifunctional Silicon Nanostructures From Biorenewable Cellulose Nanocrystals, Nancy Chen

All Dissertations

The imperative search for alternative materials to address the pressing demand for advance energy storage is underscored by the escalating environmental predicaments. Lithium-ion batteries (LIBs) with graphite anodes have become the benchmark in energy storage; however, they are approaching a saturation point in terms of energy density. Silicon emerges as a promising contender to supplant graphite, owing to its profuse availability, cost-effectiveness, and impressive specific capacity of 4200 mAh g-1. By integrating silicon anodes, LIBs stand to undergo a radical transformation, markedly diminishing in weight and size, thus heralding a novel wave of compact, lightweight energy storage systems. …


Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei 2024 Clemson University

Numerical Simulation Of Laser Induced Elastic Waves In Response To Short And Ultrashort Laser Pulses., Alireza Zarei

All Dissertations

In an era of intensified market competition, the demand for cost-effective, high-quality, high-performance, and reliable products continues to rise. Meeting this demand necessitates the mass production of premium products through the integration of cutting-edge technologies and advanced materials while ensuring their integrity and safety. In this context, Nondestructive Testing (NDT) techniques emerge as indispensable tools for guaranteeing the integrity, reliability, and safety of products across diverse industries.

Various NDT techniques, including ultrasonic testing, computed tomography, thermography, and acoustic emissions, have long served as cornerstones for inspecting materials and structures. Among these, ultrasonic testing stands out as the most prevalent method, …


Volatile Crystalline Semiconductor Core Fibers, Thomasina Zaengle 2024 Clemson University

Volatile Crystalline Semiconductor Core Fibers, Thomasina Zaengle

All Dissertations

Optical fibers play critical roles across many facets of everyday life from communications to e-commerce to sensing and security. The ubiquity of optical fibers arises from their intrinsic clarity and, as glasses, their ability to be thermally drawn at high speeds over long distances when suitably heated about their glass transition temperature. Sixteen years ago, the first thermally drawn crystalline core fibers were fabricated using the molten core method, whereby a melt is confined within a glass capillary tube that is then drawn to fiber. This opened the door to crystalline semiconductor core fibers, which are now the backbone of …


Tin-Silver As A Novel Biodegradable Metallic Biomaterial, Charley Goodwin 2024 Clemson University

Tin-Silver As A Novel Biodegradable Metallic Biomaterial, Charley Goodwin

All Dissertations

The Essure device is a non-hormonal, minimally-invasive, permanent female sterilization implant, removed from the market due to an increase in adverse events, hypothesized to be caused by corrosion of the Sn-Ag component of the implant. The goals of this dissertation were to first develop implant retrieval methods for Essure devices and surrounding tissue, documenting signs of degradation and metallic degradation products, then to characterize the electrochemical behavior of Sn-Ag in biologically representative environments and finally, to assess the biological interaction of Sn-Ag. Retrieval analyses developed successful methods, qualifying the degree of corrosion, primarily of the Sn-Ag component and finding Sn …


High Temperature Validation Of A Line Heat Source Technique For In-Pile Thermal Conductivity Determination, Katelyn Wada, Allyssa Bateman, Tony Valayil Varghese, Austin Fleming, Brian J. Jaques, David Estrada 2024 Boise State University

High Temperature Validation Of A Line Heat Source Technique For In-Pile Thermal Conductivity Determination, Katelyn Wada, Allyssa Bateman, Tony Valayil Varghese, Austin Fleming, Brian J. Jaques, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

In-pile instrumentation is critical for advancing operations and materials discovery in the nuclear industry. Ensuring optimal performance of sensors in high temperatures is the first step in demonstrating their viability in the harsh in-pile environment. This work demonstrates the high temperature capabilities of a line heat source and measurement technique previously shown to extract thermal conductivity of nuclear fuel sized samples within a laboratory environment at room temperature. This method uses a hybrid AC/DC measurement technique to obtain rapid measurements of the temperature dependent voltage change of a heater wire, which also acts as a resistance thermometer. Once the temperature …


Environment And Response Of 3d-Encapsulated Mesenchymal Stem Cells To Mechanical Loading, Augustus Greenwood 2024 Washington University in St. Louis

Environment And Response Of 3d-Encapsulated Mesenchymal Stem Cells To Mechanical Loading, Augustus Greenwood

McKelvey School of Engineering Theses & Dissertations

This thesis explores the micromechanical environment induced when cyclically compressing hydrogels via finite element modeling and experimentally on the impact of loading on mesenchymal stem cells (MSCs) when encapsulated withing 3D hydrogel matrices. Degenerative joint diseases, characterized by cartilage degradation, present significant challenges due to cartilage's limited self-repair capacity. Innovative approaches, including stem cell-based therapies and engineered biomaterials, have emerged as promising strategies for cartilage repair and regeneration. This work specifically investigates the calibration of a bioreactor, the uniformity of load response across the hydrogel constructs via finite element modeling (FEM), and the stress response of MSCs subjected to various …


Characterization Of Ceramic Powders Through Powder Rheology, Samuel Weimer 2024 University of Tennessee, Knoxville

Characterization Of Ceramic Powders Through Powder Rheology, Samuel Weimer

Doctoral Dissertations

Frequently in the literature, it has been shown that any single characterization technique is incapable of sufficiently describing the overall rheology properties of a powder. Consequently, much work has gone into exploring multivariate relationships between common rheological tests. However, such efforts have been primarily focused on powders used in pharmaceutical and food industries. Much less rheology work has been conducted for powders of other industries, such as ceramic powders used in making grinding media and crucibles. Yet, it has been shown that supplementing particle size distribution and chemical composition measurements of ceramic powders with powder rheology techniques can greatly increase …


Design And Develop Lignin Based Recyclable Copolymers For Hydrophobic Coatings, Di Xie 2024 University of Tennessee, Knoxville

Design And Develop Lignin Based Recyclable Copolymers For Hydrophobic Coatings, Di Xie

Doctoral Dissertations

Due to the abundance, renewability, biodegradability, overall hydrophobicity, good compatibility with cellulose, and anti-UV/oxidant abilities, lignin has great application potentials in hydrophobic coatings on cellulose-based substrates. However, lignin's structural heterogeneity and rigidity challenge its value-added utilization. Herein, Kraft lignin (KL), from paper mills, is fractionated into more homogeneous fractions (FL), nanosized into lignin micro-nanospheres (LMNS), chemically modified and copolymerized with other constituents to fabricate hydrophobic coating materials with improved coating performances.

To investigate structure-property relationships of lignin-based copolymers, solvent fractionation is conducted to obtain FLs with different molecular weight (MW) and hydroxyl (OH) contents to prepare copolymers by integrating with …


Development Of Novel Cesium Chloride-Based Ultrafast Inorganic Scintillators For Fast Timing Radiation Detection Applications, Daniel Rutstrom 2024 University of Tennessee, Knoxville

Development Of Novel Cesium Chloride-Based Ultrafast Inorganic Scintillators For Fast Timing Radiation Detection Applications, Daniel Rutstrom

Doctoral Dissertations

Cs2ZnCl4 [dicesium zinc tetrachloride] and Cs3ZnCl5 [tricesium zinc pentachloride] are relatively new scintillator materials that appear to be promising for use in fast-timing radiation detection applications owing to their 1 to 2 nanosecond decay times. Moreover, they offer several advantages over the state-of-the-art ultrafast inorganic scintillator BaF2 [barium fluoride]. To fully realize the potential of these novel materials, growth of crystals having improved optical quality must be demonstrated. The mechanism responsible for the ultrafast decay times, core valence luminescence (CVL), in cesium zinc chloride crystals can also be observed in other compounds containing …


Tunable Catalysts And Electrodes With High Material Utilization And Durability For Hydrogen Production, Lei Ding 2024 University of Tennessee, Knoxville

Tunable Catalysts And Electrodes With High Material Utilization And Durability For Hydrogen Production, Lei Ding

Doctoral Dissertations

Hydrogen, the future energy carrier, has gained extensive attention due to its advantages of high energy density, low weight, and zero-carbon emission. So far, hydrogen has been widely used in various fields including transportation, oil upgrading, metal refining, etc. Most hydrogen is currently produced from fossil fuels, which can cause serious environmental problems. Water electrolysis was proposed to produce clean hydrogen with carbon-free emission and only byproduct of oxygen. Among various water electrolyzer devices, the proton exchange membrane electrolyzer cell (PEMEC) shows great potential to produce green hydrogen by integrating renewable sources (solar, wind, etc.) due to its advantages of …


Multimodal Data Fusion And Machine Learning For Advancing Biomedical Applications, Md Inzamam Ul Haque 2024 University of Tennessee, Knoxville

Multimodal Data Fusion And Machine Learning For Advancing Biomedical Applications, Md Inzamam Ul Haque

Doctoral Dissertations

This dissertation delves into the intricate landscape of biomedical imaging, examining the transformative potential of data fusion techniques to refine our understanding and diagnosis of health conditions. Daily influxes of diverse biomedical data prompt an exploration into the challenges arising from relying solely on individual imaging modalities. The central premise revolves around the imperative to combine information from varied sources to achieve a holistic comprehension of complex health issues.

The chapters included here contain articles and excerpts from published works. The study unfolds through an examination of four distinct applications of data fusion techniques. It commences with refining clinical task …


Adipose Stem Cell Response To Borophosphate Bioactive Glass, Nada A. Abokefa, Bradley A. Bromet, Rebekah L. Blatt, Makenna S. Pickett, Richard K. Brow, Julie A. Semon 2024 Missouri University of Science and Technology

Adipose Stem Cell Response To Borophosphate Bioactive Glass, Nada A. Abokefa, Bradley A. Bromet, Rebekah L. Blatt, Makenna S. Pickett, Richard K. Brow, Julie A. Semon

Materials Science and Engineering Faculty Research & Creative Works

Silicate and Borate Bioactive Glasses Have Been Reported to Create Alkaline Conditions by Rapidly Releasing Ions When Reacting in Aqueous Solution. at Certain Levels, This Alkaline Solution Can Negatively Affect Cell Viability. Adding Phosphate Ions to the Glass Composition Can Control the Degradation Rate of Bioactive Glasses and Create a Neutral PH Environment. This Study Evaluated a Series of Boro phosphate Bioactive Glasses (BPBGs) with Nominal Molar Compositions 16Na2O-24CaO-XB2O3-(60-X) P2O5, Where X = 0, 40, or 60. the Phosphate (X0) Glass (PBG) Produced an Acidic Solution When Dissolved …


Study Of Reactive Distillation Equipment For Eterification Process, Abbos ELMANOV, Abdulaziz BAKHTIYOROV, Adham NORKOBILOV, Olimjon MAKSUDOV, Zarif ORIPOV 2024 Shahrisabz Branch of the Tashkent Institute of Chemical Technology, Shakhrisabz, Uzbekistan

Study Of Reactive Distillation Equipment For Eterification Process, Abbos Elmanov, Abdulaziz Bakhtiyorov, Adham Norkobilov, Olimjon Maksudov, Zarif Oripov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of this work is to study the chemical technological processes for eterification processes, and the reactive distillation unit, which carries out the reaction and separation process in one device, was chosen as the object of research. А reаctive distillаtion system is exаmined to produce for the production of Ethyl Acetate (EtAc) viа eterificаtion of acetic acid (HAc) with ethаnol. Optimizаtion methods using sensitivity analysis аre аlso conducted. Cаlculаtion of vаpor liquid equilibrium of the mixture system is done using UNIFАC model. Heat integration from the distillate stream of the column to the acid feed stream and from bottom …


Numerical Calculation Of The Flame Spreading Over A Methane Hydrate Surface, Otabek Nigmatov, Oksana Ismailova 2024 Uzbekistan-Japan Innovation Center of Youth

Numerical Calculation Of The Flame Spreading Over A Methane Hydrate Surface, Otabek Nigmatov, Oksana Ismailova

CHEMISTRY AND CHEMICAL ENGINEERING

The Methane Hydrate is expected as an energy source and is being as a medium distance transport means of natural gas alternative of LNG (Liquefied Natural Gas). During the natural gas transportation, fire accidents are concerned. In the present study, the flame spreading over a methane hydrate surface has been studied numerically as a function of hydrate surface temperature, Ts. When Ts = 173 K (-100℃), lower than the dissociation temperature (Td = 183 K (-90℃)), the flame spreading speed is around 6.5 mm/s, while the flame spreading speed at Ts = 193 K (-80℃), …


Dft Study Of Quantum Chemical Parameters Of 4-Amino-2-Mercaptobenzimidazole And Their Tautomeric Forms, Dilnoza RAHMONOVA, Alisher ESHIMBETOV, Lobar GAPUROVA, Zuhra Ch. KADIROVA, Shakhnoza KADIROVA 2024 National University of Uzbekistan, Tashkent, Uzbekistan

Dft Study Of Quantum Chemical Parameters Of 4-Amino-2-Mercaptobenzimidazole And Their Tautomeric Forms, Dilnoza Rahmonova, Alisher Eshimbetov, Lobar Gapurova, Zuhra Ch. Kadirova, Shakhnoza Kadirova

CHEMISTRY AND CHEMICAL ENGINEERING

Coordination competing donor centers, electronic and geometric structures of the 4-amino-2-mercaptobenzimidazole ligand molecule were studied using quantum chemical calculation by the DFT / 6-31G method (d, p). It was shown that during the formation of the metal complex, the ligand is coordinated through the localized nitrogen atom of the imidazole ring. In this study, the total energies (Etot) of 4-amino-2-mercaptobenzimidazole (1) and its tautomeric forms (2 and 3) were calculated. And also, the energies of boundary molecular orbitals, the energy gap between boundary MOs (ΔE) and the distribution of the total charge on atoms and boundary orbitals were determined. In …


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