Syntheses Of Ag@Pd@Pt Nanoparticles With Tunable Shell Thickness For Electrochemical Oxidation Of Formic Acid, 2016 State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Syntheses Of Ag@Pd@Pt Nanoparticles With Tunable Shell Thickness For Electrochemical Oxidation Of Formic Acid, Xiao-Dong Lin, Du-Hong Chen, Zhong-Qun Tian
Journal of Electrochemistry
In an effort to lower cost of a catalyst, the silver (Ag) core with palladium (Pd) layer then platinum (Pt) island (Ag@Pd@Pt) nanoparticles were synthesized and the electrocatalytic activity of Ag@Pd@Pt nanoparticles on formic acid was compared with that of Au@Pd@Pt nanoparticles reported previously. The results showed that the existence of a small amount of Pt could significantly improve the activity of the catalyst. When the surface coverage of Pt approached 0.5 monolayers, the activity of Ag@Pd@Pt nanoparticles reached the maximum. Though the onset potential of the electro-oxidation was slightly more positive (about 50 mV), the overall electrocatalytic activity of …
Intrinsic Interfacial Property Between High-Voltage Lini0.5Mn1.5O4 Cathode And Electrolyte, 2016 i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, Jiangsu 215125, China;University of science and technology of China, Nanoscience and Technology Institute, Suzhou, Jiangsu 215125, China;
Intrinsic Interfacial Property Between High-Voltage Lini0.5Mn1.5O4 Cathode And Electrolyte, Li Li, Jing-Jing Xu, Shao-Jie Han, Wei Lu, Li-Wei Chen
Journal of Electrochemistry
To obtain high energy density, developing high-voltage cathode materials is an effective approach. The cathode/electrolyte interface stability is the key factor for the cycle performance and safety performance of high-voltage lithium ion batteries. It is, therefore, of significant importance to study the stability of cathode/electrolyte interface. However, many reports have shown that at the cathode/electrolyte interface the cathodes were prepared by coating the mixture of active materials with a conductive additive and a binder on an Al current collector. The introduction of additives will interfere the surface morphology and component analyses, resulting in difficulty to acquire the intrinsic information at …
Lithium Plating Identification From Degradation Behaviors Of Lithium-Ion Cells, 2016 Beijing Co-innovation Center for Electric Vehicles, Beijing Institute of Technology, Beijing 100081, China
Lithium Plating Identification From Degradation Behaviors Of Lithium-Ion Cells, Jian-Bo Zhang, Lai-Suo Su, Xin-Yu Li, Hao Ge, Ya-Kun Zhang, Zhe Li
Journal of Electrochemistry
Lithium plating has huge impact on the lifetime and safety of lithium-ion cells. It is, therefore, necessary to identify lithium plating. In this study, the accelerated stress tests of lithium-ion cells were conducted under different conditions with multi-stress loads. Based on the different effects of the two major aging mechanisms, namely, SEI (Solid Electrolyte Interface) layer growth and lithium plating, on the degradation behaviors, two lithium plating identification methods of resistance-capacity plot and Arrhenius plot were employed. The experimental results revealed that the two identification methods are highly consistent with each other. Furthermore, the origins of capacity loss were distinguished …
Stm Investigation Of Oxygen Reduction Reaction On Solid Interface In Fuel Cell, 2016 CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;University of Chinese Academy of Sciences, Beijing 100049, China;
Stm Investigation Of Oxygen Reduction Reaction On Solid Interface In Fuel Cell, Zhen-Feng Cai, Bing Sun, Wen-Jie Jiang, Ting Chen, Dong Wang, Li-Jun Wan
Journal of Electrochemistry
An electrocatalyst for oxygen reduction reaction (ORR) is an important component for fuel cells. An investigation at interfacial electrochemical reactions toward ORR at a molecular scale benefits mechanistic understanding as well as rational design of catalysts. Scanning tunneling microscopy (STM) has been proven to be a powerful tool to monitor chemical reactions and to provide in-situ information about the interfacial electrochemical reactions at a molecular level. This review summarizes the recent STM studies in monitoring the interface processes such as morphological changes, molecular changes, reaction intermediates, and oxidation products. The prospects of future development in this field are outlined.
A Study On The Oxidation Of Hydrogen Peroxide At Au(111) And Au(100) Electrodes, 2016 Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei, 230026, China;
A Study On The Oxidation Of Hydrogen Peroxide At Au(111) And Au(100) Electrodes, Yong-Li Zheng, Jie Wei, Yan-Xia Chen
Journal of Electrochemistry
The oxidation reactions of hydrogen peroxide (H2O2) at Au(111) and Au(100) electrodes in 0.1 mol·L-1 HClO4 were investigated by using rotating disk electrode system. It was found that H2O2 could be readily oxidized to O2 at both Au(100) and Au(111) surfaces with the onset potential close to its equilibrium potential. In contrast, the onset overpotential for H2O2 reduction was above 0.4 V, while the onset overpotential for H2O2 oxidation at Au(100) was ca. 0.1 V more negative than that at Au(111), this is probably …
Electrochemical Behaviors And Determinations Of Terbutaline Sulfate At Poly Eriochrome Black T Modified Electrode, 2016 Department of Pharmaceutical Analysis of Fujian Medical University,Fuzhou 350108,China;The Higher Educational Key Laboratory for Nano Biomedical Technology of Fujian Province, Fujian Medical University,Fuzhou 350108,China;
Electrochemical Behaviors And Determinations Of Terbutaline Sulfate At Poly Eriochrome Black T Modified Electrode, Yan-Jie Zheng, Hong Yao, Shao-Huang Weng, Hua-Ping Peng, Shi-Wen Gong, Li Huang, Qiang Dai, Xin-Hua Lin
Journal of Electrochemistry
The poly eriochrome black T modified electrode was prepared by electropolymerization. This modified electrode was characterized by scanning electron microscopy(SEM), electrochemical impedance spectroscopy(EIS) and cyclic voltammetry (CV). The electrochemical behaviors of terbutaline sulfate were studied by CV, while the recoveries were measured by differential pulse voltammetry (DPV). The modified electrode shows excellent electrocatalytic characteristics for terbutaline sulfate. In pH 7.0 phosphate buffer solution, the oxidation peak currents obtained by DPV were linear to the terbutaline sulfate concentrations over the range of 1.2x10-7~2.0x10-6 mol•L-1. The detection limit was estimated to be 1.5x10-8 mol•L-1 and …
Chitosan/Nonahydrate Gel Derived Fe-N-Doped Porous Carbon Sheet As High-Efficient Orr Electrocatalyst, 2016 Key Laboratory of Automobile Materials, Ministry of Education and College of Materials Science and Engineering, Jilin University, Changchun 130012, China;State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130012, China);
Chitosan/Nonahydrate Gel Derived Fe-N-Doped Porous Carbon Sheet As High-Efficient Orr Electrocatalyst, Fan-Lu Meng, Xin-Bo Zhang, Jun-Min Yan
Journal of Electrochemistry
The chitosan/nonahydrate gel was used as a precursor to realize the uniform mixture of N-polymer and metal salt. After lyophilization treatment, the gel went through heat treatment and acid etch. Accordingly, the Fe-N-doped porous carbon sheet with homogenous composition and microstructure was prepared. Compared with the commercial Pt/C catalyst, the Fe-N-doped porous carbon sheet exhibited more positive onset potential and half-wave potential, higher current density, and especially, excellent durability. The power density of 318 mW·cm-2 was obtained in alkaline fuel cell with the Fe-N-doped porous carbon sheet as a cathode catalyst, which is higher than 267 mW·cm-2 with …
Synthesis Of Ultrathin Co3O4 Nanoflakes Film Material For Electrochemical Sensing, 2016 College of Electrical Engineering, Yanshan University, Qinhuangdao 066004, Hebei, China;Hebei Key Laboratory of Applied Chemistry, Yanshan University, Qinhuangdao 066004, Hebei, China.;
Synthesis Of Ultrathin Co3O4 Nanoflakes Film Material For Electrochemical Sensing, Hui-Juan Wang
Journal of Electrochemistry
Ultrathin cobalt oxide (Co3O4 ) nanoflakes film material was synthesized by using an electro-deposited cobalt layer as a raw material through a simple oxidation method and followed by a heat treatment at 350 oC. The physical characterizations of the Co3O4 nanoflakes film were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM) technologies, and the electrochemical activity was measured by cyclic voltammetry (CV). As a promising material for electrochemical sensing, the as-synthesized ultrathin Co3O4 nanoflakes film material exhibited excellent electrochemical activity for H2O …
Investigation On Laser Induced Deposition Of Cu-Based Materials At [Bmim]Bf4/Pt Electrode Interface, 2016 College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123, Jiangsu, China;
Investigation On Laser Induced Deposition Of Cu-Based Materials At [Bmim]Bf4/Pt Electrode Interface, Min-Min Xu, Jin-Hua Mei, Jian-Lin Yao, Ren-Ao Gu
Journal of Electrochemistry
By controlling the negative potential, Cu-based materials were deposited at the [BMIm]BF4/Pt electrode interface under the laser irradiation. The effects of laser power and irradiation time on the yield of deposition products were studied by using different laser powers and different irradiation time. The product yield could be directly determined by the size of deposition point through the observation from the optical microscope. Further mechanism study combined with the formula deduced that the thermal effect of the laser could make the electrode surface temperature rise 110 degrees, which can promote the occurrence of electrodeposition. By SEM characterization, the …
The Effect Of A Powered Ankle Foot Orthosis On Walking In A Stroke Subject: A Case Study, 2016 Iran University of Medical Sciences
The Effect Of A Powered Ankle Foot Orthosis On Walking In A Stroke Subject: A Case Study, Ali Pourghasem, Ismail Ebrahimi Takamjani, Mohammad Taghi Karimi, Mohammad Kamali, Mohammad Jannesari, Iman Salafian
Department of Mechanical and Materials Engineering: Faculty Publications
[Purpose] Standing and walking are impaired in stroke patients. Therefore, assisted devices are required to restore their walking abilities. The ankle foot orthosis with an external powered source is a new type of orthosis. The aim of this study was to evaluate the performance of a powered ankle foot orthosis compared with unpowered orthoses in a stroke patient.
[Subjects and Methods] A single stroke subject participated in this study. The subject was fitted with three types of ankle foot orthosis (powered, posterior leg spring, and carbon ankle foot orthoses). He was asked to walk with and without the three types …
Lucidpipe™ Power System, 2016 Construction Engineering & Management, Purdue University
Lucidpipe™ Power System, Purdue Ect Team
ECT Fact Sheets
In most gravity fed water transmission pipelines, it is desired to reduce excess pressure head to prevent undue strain on a pipeline and lower the incidence of leaks. Normally this is done with pressure reducing valves that essentially burn off this excess pressure as heat. The LucidPipe™ system converts it to low cost electricity thereby removing unwanted pressure and generating energy at the same time - energy that can be put used behind the grid or put back on the grid. The LucidPipe™ system extracts a small percentage of pressure head providing nearly invisible operation allowing water operators to fulfill …
Microstructure Control And Correlation To Creep Properties In Grade 91 Steel Weldment After Thermo-Mechanical Treatments And An Fe-30cr-3al Alloy Strengthened By Fe2nb Laves Phase, 2016 University of Tennessee, Knoxville
Microstructure Control And Correlation To Creep Properties In Grade 91 Steel Weldment After Thermo-Mechanical Treatments And An Fe-30cr-3al Alloy Strengthened By Fe2nb Laves Phase, Benjamin Allen Shassere
Doctoral Dissertations
Type IV cracking in weldments of steel pipes after creep deformation is a concern in modern fossil-fueled power plants. Two possible methods for minimizing or eliminating Type IV cracking will be discussed. The first method alters the initial microstructure of typical Grade 91 steel base metal before welding, while the second provides baseline microstructure characteristics and creep performance of a new alloy that is strengthened by the intermetallic Fe2Nb Laves phase. The initial microstructure of the Grade 91 steel can be controlled by Thermo-Mechanical Treatments, which aids in precipitation of fine (5-10 nm) MX particles in austenite before transformation to …
Mechanics Of Soft Polymers, 2016 Michigan Technological University
Mechanics Of Soft Polymers, Trisha Sain
TechTalks
Understanding the mechanics and physics of soft polymers are essential due to their widespread applications across disciplines. (e.g.-composite materials, bio mechanics, soft robotics etc.) The soft polymers in general inherent lightweight, high stretchability, extreme viscous damping and stimuli responsive behavior. Development of computational modeling strategy to predict their constitutive response, stimuli responsive behavior is indeed helpful for designing novel multifunctional soft composites, artificial mussels/tissues. In this talk I will briefly emphasize how we are developing multiscale-multiphysics based modeling methods for soft polymers to understand their macroscopic deformation mechanism, failure and other mechanical properties. The long term goal is to develop …
Aps Labs (Advanced Power Systems Research Center), 2016 Michigan Technological University
Aps Labs (Advanced Power Systems Research Center), Jeffrey D. Naber
TechTalks
Our mission is to promote & facilitate education and research in clean, efficient, and sustainable power and powertrain systems. The center was established in 2007 and in 2014 the 55,000 sq ft APSRC building located near the airport was denoted as a MTU core facility. Our new research contracts in FY2016 were over $2.5M. Our partners include automotive OEMs: GM, Ford, FCA, Toyota, Honda; Commercial OEMs: Cummins, Deere, Detroit, Isuzu, MHI; Suppliers: Delphi, Denso, Borg Warner, Hitachi; and DOE Labs: ANL, ORNL, PNNL, SNL, & INL. We have seven staff to assist in educational and R&D programs and facilities to …
Microstructural Analysis Of Thermoelastic Response, Nonlinear Creep, And Pervasive Cracking In Heterogeneous Materials, 2016 University of Maine
Microstructural Analysis Of Thermoelastic Response, Nonlinear Creep, And Pervasive Cracking In Heterogeneous Materials, Alden C. Cook
Electronic Theses and Dissertations
This dissertation is concerned with the development of robust numerical solution procedures for the generalized micromechanical analysis of linear and nonlinear constitutive behavior in heterogeneous materials. Although the methods developed are applicable in many engineering, geological, and materials science fields, three main areas are explored in this work. First, a numerical methodology is presented for the thermomechanical analysis of heterogeneous materials with a special focus on real polycrystalline microstructures obtained using electron backscatter diffraction techniques. Asymptotic expansion homogenization and finite element analysis are employed for micromechanical analysis of polycrystalline materials. Effective thermoelastic properties of polycrystalline materials are determined and compared …
Me-Em Enewsbrief, December 2016, 2016 Michigan Technological University
Me-Em Enewsbrief, December 2016, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Department of Mechanical Engineering-Engineering Mechanics eNewsBrief
No abstract provided.
Development Of Lignin Carbon Fiber And Reinforced Composites, 2016 University of Tennessee, Knoxville
Development Of Lignin Carbon Fiber And Reinforced Composites, Nathan Kieran Meek
Masters Theses
The aim of this work is to develop lignin carbon fiber for composite applications. This included mechanical testing of single lignin carbon fiber (LCF), interfacial shear strength determination for LCF-resin systems using single fiber fragmentation, x-ray diffraction for the evaluation of microstructural parameters, and finally composite manufacturing and testing. Through these focused areas of analysis, the carbon fiber is thoroughly characterized and composite performance is evaluated. This effort was a collaboration with the Center for Renewable Carbon (CRC) and the Civil and Environmental Engineering Department. LCF produced by the CRC resulted in fibers having tensile strength of 250-800 MPa and …
Self-Patterning Gd Nano-Fibers In Mg-Gd Alloys, 2016 Shanghai Jiao Tong University
Self-Patterning Gd Nano-Fibers In Mg-Gd Alloys, Yangxin Li, Jian Wang, Kaiguo Chen, Meiyue Shao, Yao Shen, Li Jin, Guo-Zhen Zhu
Department of Mechanical and Materials Engineering: Faculty Publications
Manipulating the shape and distribution of strengthening units, e.g. particles, fibers, and precipitates, in a bulk metal, has been a widely applied strategy of tailoring their mechanical properties. Here, we report self-assembled patterns of Gd nano-fibers in Mg-Gd alloys for the purpose of improving their strength and deformability. 1-nm Gd nano-fibers, with a 〈c〉-rod shape, are formed and hexagonally patterned in association with Gd segregations along dislocations that nucleated during hot extrusion. Such Gd-fiber patterns are able to regulate the relative activities of slips and twinning, as a result, overcome the inherent limitations in strength and ductility of Mg alloys. …
Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, 2016 University of Southern Mississippi
Structure-Property Relationships Of Polyisobutylene-Block-Polyamide Thermoplastic Elastomers, Morgan Dunn Heskett
Master's Theses
Thermoplastic elastomers (TPEs) are a class of polymer fit for a wide variety of applications due to their customizability. In the synthesis of these types of materials, an elastically-performing polymer, deemed the “soft block,” is combined with a stiffer “hard block” polymer, each of which can be selected based on their own specific properties in order to achieve desired material behavior in the final copolymer. Recently, the use of polyisobutylene as a soft block in combination with a polyamide hard block has been investigated for use in TPE synthesis. While the material showed some promising behavior, many properties were still …
Sulfate Resistance Of Nanosilica Contained Portland Cement Mortars, 2016 University of Nevada, Las Vegas
Sulfate Resistance Of Nanosilica Contained Portland Cement Mortars, Iani Batilov Batilov
UNLV Theses, Dissertations, Professional Papers, and Capstones
Soils, sea water and ground water high in sulfates are commonly encountered hostile environments that can attack the structure of concrete via chemical and physical mechanisms which can lead to costly repairs or replacement. Sulfate attack is a slow acting deteriorative phenomenon that can result in cracking, spalling, expansion, increased permeability, paste-to-aggregate bond loss, paste softening, strength loss, and ultimately, progressive failure of concrete. In the presented research study, Portland cement (PC) mortars containing 1.5% to 6.0% nanosilica (nS) cement replacement by weight were tested for sulfate resistance through full submersion in sodium sulfate to simulate external sulfate attack. Mortars …