Mechanics of Materials Commons^™

Achieving High Efficiency Laminated Polymer Solar Cell With Interfacial Modified Metallic Electrode And Pressure Induced Crystallization, Yongbo Yuan, Yu Bi, Jinsong Huang

Mechanical & Materials Engineering Faculty Publications

We report efficient laminated organic photovoltaic device with efficiency approach the optimized device by regular method based on Poly(3-hexylthiophene-2,5-diyl) and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PCBM). The high efficiency is mainly attributed to the formation of a concrete polymer/metal interface mechanically and electrically by the use of electronic-glue, and using the highly conductive and flexible silver film as anode to reduce photovoltage loss and modifying its work function for efficiency hole extraction by ultraviolet/ozone treatment, and the pressure induced crystallization of PCBM.

Intermediate Layers In Tandem Organic Solar Cells, Yongbo Yuan, Jinsong Huang, Gang Li

Mechanical & Materials Engineering Faculty Publications

Tandem structures can boost the efficiency of organic solar cell to more than 15%, compared to the 10% limit of single layer bulk heterojunction devices. Design and fabricating of intermediate layers plays a very important role to achieve high device performance. This article will review the main experimental progresses of tandem organic solar cells, and focus on the intermediate layers (charge recombination layers) in both thermal evaporated and solution processed organic tandem solar cell devices.

A Model Of Giant Vacuole Dynamics In Human Schlemm’S Canal Endothelial Cells, Ryan M. Pedrigi, David Simon, Ashley Reed, W. Daniel Stamer, Darryl R. Overby

Mechanical & Materials Engineering Faculty Publications

Aqueous humour transport across the inner wall endothelium of Schlemm’s canal likely involves flow through giant vacuoles and pores, but the mechanics of how these structures form and how they influence the regulation of intraocular pressure (IOP) are not well understood. In this study, we developed an in vitro model of giant vacuole formation in human Schlemm’s canal endothelial cells (HSCECs) perfused in the basal-to-apical direction (i.e., the direction that flow crosses the inner wall in vivo) under controlled pressure drops (2 or 6 mmHg). The system was mounted on a confocal microscope for time-lapse en face imaging, and cells …

In Vitro Models For Glaucoma Research: Effects Of Hydrostatic Pressure, Yuan Lei, Shadi Rajabi, Ryan M. Pedrigi, Darryl R. Overby, A. Thomas Read, C. Ross Ethier

Mechanical & Materials Engineering Faculty Publications

PURPOSE. The response of cells (e.g., optic nerve head [ONH] cells) to mechanical stress is important in glaucoma. Studies have reported the biological effects of hydrostatic pressure on ONH cells cultured on a rigid substrate. An apparatus, designed to independently vary hydrostatic pressure and gas tension (including oxygen tension) in culture medium, was used to evaluate the effects of pressure and tension on cell migration, shape, and α-tubulin architecture in a transformed cell line (DITNC1 rat cortical astrocytes).

METHODS. During the assay period, cells were exposed to one of four experimental configurations: (1) control pressure and control gas tension; (2) …

Nanomechanical Analysis Of Insulinoma Cells After Glucose And Capsaicin Stimulation Using Atomic Force Microscopy, Ruiguo Yang, Ning Xi, King Wai-Chu Lai, Bei-Hua Zhong, Carmen Kar-Man Fung, Chen-Geng Qu, Donna H. Wang

Mechanical & Materials Engineering Faculty Publications

Aim: Glucose stimulates insulin secretion from pancreatic islet β cells by altering ion channel activity and membrane potential in the β cells. TRPV1 channel is expressed in the β cells and capsaicin induces insulin secretion similarly to glucose. This study aims to investigate the biophysical properties of the β cells upon stimulation of membrane channels using an atomic force microscopic (AFM) nanoindentation system.

Methods: ATCC insulinoma cell line was used. Cell stiffness, a marker of reorganization of cell membrane and cytoskeleton due to ion channel activation, was measured in real time using an integrated AFM nanoindentation system. Cell height that …

Impact Of Elliptical Trainer Ergonomic Modifications On Perceptions Of Safety, Comfort, Workout, And Usability For People With Physical Disabilities And Chronic Conditions, Judith M. Burnfield, Yu Shu, Thad W. Buster, Adam P. Taylor, Carl A. Nelson

Mechanical & Materials Engineering Faculty Publications

Background The popularity of elliptical training has grown in rehabilitation, fitness, and home settings as a means for improving fitness and walking, yet many people with physical disabilities and chronic conditions experience difficulties when trying to use elliptical trainers.

Objective The purpose of this study was to compare, for people with disabilities and chronic conditions, perceptions of safety, comfort, workout, and usability of 4 elliptical trainers before and after the development of a set of low-cost adaptations.

Design This study was a quasi-experimental repeated-measures investigation.

Methods Twenty adults with diverse medical conditions and functional abilities evaluated 4 elliptical trainers for …

Dispersive Wave Equations For Solids With Microstructure, A. Berezovski, Juri Engelbrecht, Mihhail Berezovski

Publications

The dispersive wave motion in solids with microstructure is considered in the one-dimensional setting in order to understand better the mechanism of dispersion. It is shown that the variety of dispersive wave propagation models derived by homogenization, continualisation, and generalization of continuum mechanics can be unified in the framework of dual internal variables theory.

Freeze-Thawing Of Polyester/E-Glass As An Evaluation Of An Astm International Test Standard Proposal, Stefan Mauritz Strandlund

Electronic Theses and Dissertations

American Composites Manufacturers Association (ACMA) reported in 2009 that the four major sectors currently utilizing fiber reinforced polymers (FRP) are construction, corrosion, marine, and transportation in descending order of total FRP shipped. All of these sectors are known to be billion dollar industries and they are all involved with applications subjected to freezing and thawing. FRP encompass many characteristics that are beneficial to these sectors and also in resisting this exposure. ASTM International has yet not developed a standard to test FRP materials resistance to freeze-thaw (FT) cycling exposure. The D20.18.02 committee of the ASTM is in the process of …

Microstructural Architecture Developed In The Fabrication Of Solid And Open-Cellular Copper Components By Additive Manufacturing Using Electron Beam Melting, Diana Alejandra Ramirez

Open Access Theses & Dissertations

The fabrication of Cu components were first built by additive manufacturing using electron beam melting (EBM) from low-purity, atomized Cu powder containing a high density of Cu2O precipitates leading to a novel example of precipitate-dislocation architecture. These microstructures exhibit cell-like arrays (1-3µm) in the horizontal reference plane perpendicular to the build direction with columnar-like arrays extending from ~12 to >60 µm in length and corresponding spatial dimensions of 1-3 µm. These observations were observed by the use of optical metallography, and scanning and transmission electron microscopy. The hardness measurements were taken both on the atomized powder and the Cu components. …

Fabrication And Characterization Of Nanocrystalline Yttrium Oxide Thin Films For Electronic Device Applications, Mudavakkat Vikas Haridas

Open Access Theses & Dissertations

This thesis presents the optimization of growth conditions for fabricating nanocrystalline Yttrium Oxide (Y2O3) thin films on silicon and optical grade, high quality quartz substrates in order to study its structural, optical and electrical properties for electronic device applications.

Commercially Y2O3 has proven to be difficult to fabricate at high quality due to its high temperature growth requirements and the need to alter established fabrication methods for electronic devices. A high temperature requirement for high quality poses a problem for research and analysis. This calls upon for an optimization of the growth conditions to facilitate fabrication of thin films for …

Reverse Logic - Safety Of Spent Nuclear Fuel Disposal, Antti Lempinen, Marianne Silvan-Lempinen

Antti Lempinen

No abstract provided.

Patterning Of Alloy Precipitation Through External Pressure, Jack A. Franklin

Publicly Accessible Penn Dissertations

Due to the nature of their microstructure, alloyed components have the benefit of meeting specific design goals across a wide range of electrical, thermal, and mechanical properties. In general by selecting the correct alloy system and applying a proper heat treatment it is possible to create a metallic sample whose properties achieve a unique set of design requirements. This dissertation presents an innovative processing technique intended to control both the location of formation and the growth rates of precipitates within metallic alloys in order to create multiple patterned areas of unique microstructure within a single sample. Specific experimental results for …

Mapping Trabecular Bone Fabric Tensor By In Vivo Magnetic Resonance Imaging, Michael J. Wald

Publicly Accessible Penn Dissertations

The mechanical competence of bone depends upon its quantity, structural arrangement, and chemical composition. Assessment of these factors is important for the evaluation of bone integrity, particularly as the skeleton remodels according to external (e.g. mechanical loading) and internal (e.g. hormonal changes) stimuli. Micro magnetic resonance imaging (µMRI) has emerged as a non-invasive and non-ionizing method well-suited for the repeated measurements necessary for monitoring changes in bone integrity. However, in vivo image-based directional dependence of trabecular bone (TB) has not been linked to mechanical competence or fracture risk despite the existence of convincing ex vivo evidence. The objective of this …

Anomalous Loss Of Toughness Of Work Toughened Polycarbonate, Shawn E. Meagher

Engineering Mechanics Dissertations & Theses

Glassy polymers such as polycarbonate (PC) can be toughened through compressive plastic deformation. The increase in toughness is substantial, showing as much as a fifteen fold increase in the amount of dissipated energy during failure for samples compressed to 50% plastic strain. This toughness increase can be reversed through thermal aging at temperatures below the glass transition temperature (T_g = 147°C).

The combined effect of plastic compression and thermal aging has been studied using Charpy, Single Edge Notch Bending (SENB), and Compact Tension (CT) tests. The tests mapped the response of samples cut along different orientations relative to the …

Effect Of Moisture Absorption On The Sinter Quality Of Central Solenoid (Cs) Coil Pack, Zeshaan Sher Mohammed

Masters Theses

Fusion energy has been said to be the solution to all the world’s energy problems. The International Thermonuclear Experimental Reactor (ITER) is the flagship project to demonstrate the feasibility of fusion energy. The Central Solenoid (CS), an important component of the reactor, is needed to induce plasma current, initiate, ramp-up, ramp-down, and sustain plasma in a very controlled manner. In order to achieve this, the CS coil packs must be manufactured under controlled conditions. The CS conductor is an advanced cable-in-conduit Nb3Sn superconductor. The CS cable will be made in long continuous sections but with thousands of meter of cable …

Processing And Composition Effects On The Fracture Behavior Of Spray-Formed 7xxx Series Al Alloys, Mala M. Sharma, Constance W. Ziemian, Timothy J. Eden

Faculty Journal Articles

The fracture properties of high-strength spray-formed Al alloys were investigated, with consideration of the effects of elemental additions such as zinc,manganese, and chromium and the influence of the addition of SiC particulate. Fracture resistance values between 13.6 and 25.6 MPa (m)^1/2 were obtained for the monolithic alloys in the T6 and T7 conditions, respectively. The alloys with SiC particulate compared well and achieved fracture resistance values between 18.7 and 25.6 MPa (m)^1/2. The spray-formed materials exhibited a loss in fracture resistance (KI) compared to ingot metallurgy 7075 alloys but had an improved
performance compared to high-solute powder …

Deformation Waves In Microstructured Materials: Theory And Numerics, Juri Engelbrecht, Arkadi Berezovski, Mihhail Berezovski

Publications

A linear model of the microstructured continuum based on Mindlin theory is adopted which can be represented in the framework of the internal variable theory. Fully coupled systems of equations for macro-motion and microstructure evolution are represented in the form of conservation laws. A modification of wave propagation algorithm is used for numerical calculations. Results of direct numerical simulations of wave propagation in periodic medium are compared with similar results for the continuous media with the modelled microstructure. It is shown that the proper choice of material constants should be made to match the results obtained by both approaches

Diffuse Ultrasonic Scattering In Advanced Composites, Christer Stenström

Engineering Mechanics Dissertations & Theses

Non destructive testing (NDT) is a noninvasive technique used for characterization and inspection of the integrity of objects. NDT is an important tool for research, manufacturing monitoring and in-service inspections. Ultrasonic testing is the most used NDT technique, which for advanced composites can identify several types of defects, like delamination and interlaminar cracks. Diffuse ultrasonics has shown to be able to extract information at the microscale of metals and therefore it is believed it can be used for advanced composites to extract microstructural information, i.e. at the level of fibers.

In this thesis, diffuse ultrasonic methods, together with spatial variance …

Characterization, Modeling, And Consequences Of The Development During Plastic Flow Of Large Anisotropy In The Wave-Speeds, Quentin Fichot

Engineering Mechanics Dissertations & Theses

There is a substantial change in the anisotropy of some glassy polymers when they are subjected to large plastic deformations. The most pronounced case probably is seen in polycarbonate (PC), which is a tough thermoplastic used for many structural applications, including as a protective transparent armor for such applications as bulletproof glass. This development of anisotropy in the elastic response can be of the same order as the applied strains, and, therefore, becomes important in problems that show substantial plastic flow. In spite of this, this characteristic of glassy polymers has not been included in the current models. We propose …

Methods For Characterizing Mechanical Properties Of Wood Cell Walls Via Nanoindentation, Yujie Meng

Masters Theses

Nanoindentation is a method of contacting a material whose mechanical properties are unknown with another material whose properties are known. Nanoindentation has the advantage of being able to probe a material’s microstructure while being sensitive enough to detect variations in mechanical properties. However, nanoindentation has some limitations as a testing technique due to the specific formation and structure of some biomaterials. The main objective of this research is to identify any factors that influence the nanoindentation measurement of wood cell walls (a typical biomaterial).

The function of the embedding media in describing the properties of wood cells is poorly understood. …