Catalysis and Reaction Engineering Commons^™

Process Of Combined Oxidation Of Co And So2 In Waste Gases Of Non‐Ferrous Smelters At Platinum Glass‐Fiber Catalyst, Sergey V. Vanag, Andrey N. Zagoruiko

Andrey N Zagoruiko

The work is dedicated to the development of the efficient catalyst for the oxidation of CO in presence of significant amounts of SO2. It was experimentally shown that the Pt/Zr-Si glas-fiber-based catalyst is capable to provide complete CO conversion in SO2 presence at temperatures less 300 С, at the same time showing high resistance to deactivation. Application of such catalyst in the reverse-process will allow to raise essentially efficiency of purification of waste metallurgical gases from SO2 under presence of significant amounts (up to 1-2% vol.) of CO.

New Developments In The Area Of Nonstationary And Sorption-Enhanced Catalytic Processes, Andrey N. Zagoruiko

Andrey N Zagoruiko

The presentation is dedicated to catalytic processes performed under artificially created catalyst nonstationarity. It is shown that the highest technological effect can be achieved for a controlled combination of the thermal nonstationarity with the composition nonstationarity of the catalyst surface. Prospective for application of unsteady catalytic and sorption-catalytic processes are analyzed for different case applications: VOC incineration, hydrogen production by steam conversion of hydrocarbons and organic feedsctock, selective anaerobic oxidation of hydrocarbons. In general, unsteady state and sorption-catalytic ideology discovers new degrees of freedom for process development and may become the basement for new generation of highly-efficient catalytic technologies in …

Applied Control Strategies At A Cogeneration Plant, Joseph William Burns

Master's Theses

The purpose of this paper is to demonstrate the effectiveness of “classical strategies for dynamic control” on authentic cogeneration processes. These strategies are applied to several processes at the University of Connecticut’s cogeneration plant. Case studies of their applications are presented in this paper. Strategies that are applied include the following:

1) The classical SISO feedback structure

2) The First Order Plus Dead Time (FOPDT) process model

3) The Internal Model Control (IMC) correlations for PI controller tuning

4) Static feed forward with feedback trim

5) Cascade Control

A Study Of Red./Ox. Thermodynamic And Catalytic Properties Of Metal Oxide Materials, Ivan S. Baldychev

Publicly Accessible Penn Dissertations

Redox thermodynamic properties and catalytic activities of metal oxides were studied to gain insight into the fundamental relationships between those properties. Catalysts based on iron oxides, vanadium oxides, and molybdenum oxides were studied because of their industrial importance to the water-gas-shift and partial-oxidation reactions.

Redox properties of 5wt% and 15wt% V2O5/Al2O3 catalysts calcined at 753 K and 973 K were measured using coulometric titration at 748 K. 5wt% V2O5/Al2O3 was found to be thermally stable and its reduction from V+5 to V+4 occurred at P(O2) values between 10-4 and 10-19 atm and from V+4 to V+3 at a PO2 of …

Evaluation Of Uv Absorption Parameters In An Aqueous Photocatalytic Slurry Reactor Using Monte Carlo Simulations And Macroscopic Balances, Jesus Moreira Del Rio, Benito Serrano Rosales, Aaron Ortiz Gomez, Hugo De Lasa

Jesus Moreira del Rio

No abstract provided.

Roles Of Non-Thermal Plasma In Gas-Phase Glycerol Dehydration Catalyzed By Supported Silicotungstic Acid, Lu Liu

Doctoral Dissertations

Acrolein is an indispensable chemical intermediate with a rising demand in recent years. The concern of the increase of propylene prices due to the shrinking supply of nonrenewable crude oil makes the acid-catalyzed gas-phase glycerol dehydration to acrolein a prime candidate for research. Our analysis showed that the sustainable acrolein production from glycerol was both technically and economically viable. Alumina2700^® (Al) and Silica1252^® (Si) loaded with silicotungstic acid (HSiW) possessed distinct features while provided equally good acrolein yield (73.86mol% and 74.05mol%, respectively) optimally.

Due to the unique non-equilibrium characteristics, non-thermal plasma (NTP) could promote a variety of chemical …

Pigments For Improving Plant Health In Organic Systems, Gregory Keith Bartley Jr.

Gregory Keith Bartley Jr.

Photosynthesis, arguably the most important biological process on earth, solely relies on the ability of pigments to capture, utilize, and convert the sun‟s energy to form life. The adequate conversion of light into harvestable food, fuel, and fiber regulates rates of population and economic growth. In order to meet the expanding needs of humanity with the earth‟s potential for agricultural production, new sustainable techniques for increased photosynthetic efficiency in plants must be implemented. The earth's pattern of light exposure is extremely dynamic, exhibiting constant changes in quantity and quality throughout time and space. For photosynthetic organisms, this meant evolving various …

New Nanosystem Mixed Reactor For Urban Wastewater Treatment, Masoud Rastegar

Masoud Rastegar

No abstract provided.

Kinetics Of The Bray-Liebhafsky Oscillatory Reaction Perturbed By Polymer Supported Cobalt Catalyst, Zeljko D. Cupic

Zeljko D Cupic

The Bray-Liebhafsky (BL) oscillatory reaction generated in the batch reactor at 62-68 degree C was perturbed by cobalt(II)-nitrate, supported on the macroreticular copolymer of poly-4-vinylpyridine with divinylbenzene (Co-PVPDVB). The kinetic data was analyzed of the complex pathways of the hydrogen peroxide decomposition in the examined BL reaction. The obtained results confirm that the kinetics of the BL reaction in the presence Co-PVPDVB comes partially from the Co-catalyst and partially from the macroreticular copolymer support.

Hydrodynamic Characteristics Of A Novel Circulating Fluidized Bed Steam Reformer Operating In The Fast Fluidization Regime, Moataz Bellah M. Mousa, Seif-Eddeen K. Fateen, Essam A. Ibrahim

Seif-Eddeen K Fateen

Circulating Fluidized Bed Steam Reformers (CFBSRs) represent an important alternative for the production of syngas for the Fisher-Tropsch (FT) process and for hydrogen production. Most research regarding this novel CFBSRs did not consider its hydrodynamic characteristics. In this work, the riser Computational Fluid Dynamics (CFD) simulations were investigated using two phase Eulerian-Eulerian approach coupled with kinetic theory of granular flow with k-epsilon model to describe the turbulence of each phase. The model equations were solved via the commercial CFD package FLUENT, which uses the finite volume numerical approach. Cold flow simulations were carried out under the fast fluidization regime and …

Applications Of A 3-D Cfb Model On Oxycombustion, Gasification And Calcinator In Calcium Looping, Kari Myöhänen, Timo Hyppänen, Markku Nikku, Matti Koski, Jarno Parkkinen

Kari Myöhänen

No abstract provided.

Study On The Glycerolysis Reaction Of High Free Fatty Acid Oils For Use As Biodiesel Feedstock, João F. Gomes

João F Gomes

Biodiesel is the main alternative to fossil diesel and it may be produced from different feedstocks such as semi-refined vegetable oils, waste frying oils or animal fats. However, these feedstocks usually contain significant amounts of free fatty acids (FFA) that make them inadequate for the direct base catalyzed transesterification reaction (where the FFA content should be lower than 4%). The present work describes a possible method for the pre-treatment of oils with high content of FFA (20 to 50%) by esterification with glycerol. In order to reduce the FFA content, the reaction between these FFA and an esterification agent is …

Design Of A New Test Chamber For Evaluation Of The Toxicity Of Rubber Infill, João F. Gomes

João F Gomes

A test chamber was projected and built (according to ISO 16000-9 Standard) to simulate atmospheric conditions experienced by rubber infill (when applied in synthetic turf pitches) and measure accurately the airborne emissions of pollutants such as dusts and volatile organic compounds (VOC), as well as pollutants present in leacheates. It should be pointed out that standard ISO 16000-9 is only concerned with the determination of the emission of VOC from building products and furnishing (not specific of synthetic turf materials), while other standards are concerned with the emission of leacheates only. This procedure is to be considered as a technical …

What Is A Chemical Engineer ?, João F. Gomes

João F Gomes

No abstract provided.

On The Toxicological Effects Of Airborne Nanoparticles From Welding Processes, João F. Gomes

João F Gomes

No abstract provided.

Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr.

Eng-Poh Ng

Lubricants play a significant part in current environmental considerations since they are an integral and indispensable component of modern technology. The production, application and disposal of the lubricants have to follow increasingly strict requirements for protecting the environment and living organisms. In this respect, molecular sieve (LTL type zeolite) is investigated as a potential environmentally friendly alternative to traditional antioxidant additives for lubricant oils. Accelerated oxidation experiments using pure base oil and additivated base oil in the presence of the LTL molecular sieve are carried out in parallel, and the oxidation processes are monitored by FT-IR spectroscopy, spectrophotometry, chromatography, total …

Termodynamika Procesowa (Dla Me Aparatura Procesowa) Ćw., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

The Analysis Of Heat Transfer In A Gas-Gas Heat Exchanger Operated Under A Heat-Recirculating Mode, Mariusz Salaniec, Wojciech M. Budzianowski

Wojciech Budzianowski

The present paper presents the analysis of heat transfer in a gas-gas heat exchanger operated in a heat-recirculating mode.

An Overview Of Technologies For Upgrading Of Biogas To Biomethane, Wojciech M. Budzianowski

Wojciech Budzianowski

The present contribution presents an overview of technologies available for upgrading of biogas to biomethane. Technologies under study include pressure swing adsorption (PSA), high-pressure water wash (HPWW), reactive absorption (RA), physical absorption (PA), membrane separation (MS) and cryogenic separation (CS).

Influence Of Energy Policy On The Rate Of Implementation Of Biogas Power Plants In Germany During The 2001-2010 Decade, Izabela Chasiak, Wojciech M. Budzianowski

Wojciech Budzianowski

The current article describes energy policy tools, which caused intensive development of biogas-based power generation in Germany during the 2001-2010 decade. The German system of financial support to biogas power plants is presented in details. It is shown that in Germany, i.e. in a country characterised by similar climate and potentials to renewable energy to Poland, biogas power plants cover 10,7% of electricity demands in 2010, while all renewable energy sources cover only 5,4% of electricity demands. It is emphasised that under favourable Polish energy policy, the development of biogas energy can be very rapid.